Application of Amine Salts of Glycyrrhizinic Acid for Prevention of Grape Rot during the Storage Period

M. I. Shatirova, R. A. Asadullayev, Sh. F. Nagiyeva
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Abstract

Rots of various origins account for a significant part of the losses of grapes both during the growing season and during long-term storage. Along with traditional methods, to prevent damage to grapes during storage, environmentally friendly preparations were tested, the raw materials for which were licorice roots (Glycyrrhiza). The corresponding salts of glycyrrhizic acid were synthesized by the interaction of glycyrrhizic acid with o-phenylenediamine and methyl ester of p-aminobenzoic acid in a medium of dry acetone. The universal grape variety Moldova was chosen as the object of the study, and the storage was carried out in a refrigerator at a temperature of 5°C for 4 months. To prevent the development of pathogenic microflora, granules of sodium metabisulfite (Na2S2O5), o-phenylenediamine glycyrrhizic acid, and methyl ether of p-aminobenzoic acid, as well as granules of dried crushed licorice root, were used at the rate of 20 g per 7–8 kg of grapes. When using Na2S2O5 to protect against the effects of harmful microflora, there were no losses either from rotting or from tearing the berries from the crest of the bunch, and the color and consistency of the berries remained the same as during storage. The effectiveness of the tested preparations with the same method of application was somewhat less: in the variant with licorice root granules, losses amounted to more than half, about half of the product with o-phenylenediamine glycyrrhizic acid (compound 2), and the yield of standard products was slightly more than 70% of the batch stored with methyl ester of p-aminobenzoic acid (compound 3).

Abstract Image

应用甘草酸胺盐预防葡萄贮藏期腐烂病
摘 要 在葡萄的生长季节和长期储藏过程中,各种来源的葡萄根造成了很大一部分损失。为了防止葡萄在贮藏过程中受损,除了传统方法外,还测试了环境友好型制剂,其原料是甘草根(Glycyrrhiza)。通过甘草酸与邻苯二胺和对氨基苯甲酸甲酯在干丙酮介质中的相互作用,合成了相应的甘草酸盐。研究对象选择了摩尔多瓦的通用葡萄品种,并在 5°C 的冰箱中贮藏了 4 个月。为防止病原微生物菌群的发展,每 7-8 公斤葡萄使用 20 克焦亚硫酸钠(Na2S2O5)颗粒、邻苯二胺甘草酸、对氨基苯甲酸甲醚以及干碎甘草根颗粒。在使用 Na2S2O5 防止有害微生物的影响时,浆果没有因腐烂或从果串顶端撕裂而造成损失,而且浆果的颜色和稠度与储存期间保持一致。采用相同施用方法的试验制剂的效果稍差:在使用甘草根颗粒的变体中,损失超过一半,在使用邻苯二胺甘草酸(化合物 2)的产品中损失约一半,在使用对氨基苯甲酸甲酯(化合物 3)储存的批次中,标准产品的产量略高于 70%。
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