{"title":"Ignition and combustion characteristics of aluminum-based fluorine-containing composite powder","authors":"Peini Xie, Xueqin Liao, Jianzhong Liu","doi":"10.1016/j.tca.2024.179757","DOIUrl":null,"url":null,"abstract":"<div><p>To improve the combustion characteristics of micron-sized aluminum (Al) powder, a composite powder was prepared by doping a small amount (15 wt%) of magnesium fluoride (MgF<sub>2</sub>), polytetrafluoroethylene (PTFE), and fluorinated graphite (FG) into the aluminum powder through solution dispersion method. The physical phase composition, micro morphology, thermal reactivity, and combustion performance of the composite powders were also characterized. The findings suggest that the promoting effect of the three fluorides on aluminum combustion can be ranked in the following descending order: FG > PTFE > MgF<sub>2</sub>. The fluorides can to erode the Al<sub>2</sub>O<sub>3</sub> shell layer directly, thus creating cracks and reaction pathways for the Al core enclosed within the shell. Moreover, the gasification of AlF<sub>3</sub> within the combustion products can escape from the surface of Al particles and promote the oxidation combustion of the exposed aluminum, which enhances the diffusion reaction on the active aluminum surface.</p></div>","PeriodicalId":23058,"journal":{"name":"Thermochimica Acta","volume":"736 ","pages":"Article 179757"},"PeriodicalIF":3.1000,"publicationDate":"2024-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thermochimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040603124000960","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
To improve the combustion characteristics of micron-sized aluminum (Al) powder, a composite powder was prepared by doping a small amount (15 wt%) of magnesium fluoride (MgF2), polytetrafluoroethylene (PTFE), and fluorinated graphite (FG) into the aluminum powder through solution dispersion method. The physical phase composition, micro morphology, thermal reactivity, and combustion performance of the composite powders were also characterized. The findings suggest that the promoting effect of the three fluorides on aluminum combustion can be ranked in the following descending order: FG > PTFE > MgF2. The fluorides can to erode the Al2O3 shell layer directly, thus creating cracks and reaction pathways for the Al core enclosed within the shell. Moreover, the gasification of AlF3 within the combustion products can escape from the surface of Al particles and promote the oxidation combustion of the exposed aluminum, which enhances the diffusion reaction on the active aluminum surface.
期刊介绍：
Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application.
The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta.
The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas:
- New and improved instrumentation and methods
- Thermal properties and behavior of materials
- Kinetics of thermally stimulated processes
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