Isotopic Shifts of Vibrational-Rotational Lines of SO2

IF 0.9 Q4 OPTICS

Atmospheric and Oceanic Optics Pub Date : 2024-04-26 DOI:10.1134/S1024856023700021

A. D. Bykov, B. A. Voronin

引用次数: 0

Abstract

Simple isotopic relations between the energy levels of ³²S¹⁶O₂, ³³S¹⁶O₂, and ³⁴S¹⁶O₂ isotopologues and of other isotopic variants are applied to calculations of vibrational-rotational energy levels. To estimate the accuracy of these isotopic relations, we calculated line centers in the microwave spectrum of ³⁶S¹⁶O₂ isotopologue and compared them with measured ones. The comparison shows their quite satisfactory agreement at a level of 10⁻⁴ cm⁻¹. Vibrational-rotational energy levels of sulfur dioxide isotopologues ^XS¹⁶O₂, X = 35–38, are presented for five lower vibrational states up to J = 9.

Abstract Image

查看原文本刊更多论文

二氧化硫振动-旋转线的同位素位移

摘要-32S16O2、33S16O2 和 34S16O2 同位素能级与其他同位素变体能级之间的简单同位素关系被应用于振动-旋转能级的计算。为了估算这些同位素关系的准确性，我们计算了 36S16O2 同素异形体微波光谱中的线中心，并与测量值进行了比较。比较结果表明，在 10-4 cm-1 的水平上，它们的一致性相当令人满意。我们给出了 XS16O2（X = 35-38）二氧化硫同素异形体的振动-旋转能级，包括 J = 9 以下的五个低振动态。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Atmospheric and Oceanic Optics OPTICS-

CiteScore

2.40

自引率

42.90%

发文量

期刊介绍： Atmospheric and Oceanic Optics is an international peer reviewed journal that presents experimental and theoretical articles relevant to a wide range of problems of atmospheric and oceanic optics, ecology, and climate. The journal coverage includes: scattering and transfer of optical waves, spectroscopy of atmospheric gases, turbulent and nonlinear optical phenomena, adaptive optics, remote (ground-based, airborne, and spaceborne) sensing of the atmosphere and the surface, methods for solving of inverse problems, new equipment for optical investigations, development of computer programs and databases for optical studies. Thematic issues are devoted to the studies of atmospheric ozone, adaptive, nonlinear, and coherent optics, regional climate and environmental monitoring, and other subjects.