Advancing electrochemical CO2 reduction: Insights from operando attenuated total reflectance surface-enhanced infrared absorption spectroscopy analysis

IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL
Sojung Park, Wooyul Kim
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引用次数: 0

Abstract

Cu-based electrodes have been at the forefront of research on the electrochemical reduction of CO2 for several decades owing to their ability to generate multi-carbon products. Various innovative approaches, including alloying, doping, and surface modification, have been used to develop catalysts with superior selectivity, activity, and durability. Despite these developments, the commercialization of Cu-based electrocatalysts for the CO2 reduction reaction remains elusive. This review provides comprehensive insights into catalyst design and discusses methodologies using in situ surface-enhanced infrared absorption spectroscopy for the validation of newly designed catalysts, particularly those developed considering the information presented herein.

推进电化学二氧化碳还原:操作步长衰减全反射表面增强红外吸收光谱分析的启示
几十年来,由于铜基电极能够生成多种碳产品,因此一直处于二氧化碳电化学还原研究的前沿。各种创新方法,包括合金化、掺杂和表面改性,已被用于开发具有卓越选择性、活性和耐久性的催化剂。尽管取得了这些进展,但用于二氧化碳还原反应的铜基电催化剂的商业化仍然遥遥无期。本综述提供了催化剂设计的全面见解,并讨论了使用原位表面增强红外吸收光谱验证新设计催化剂的方法,特别是考虑到本文提供的信息而开发的催化剂。
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来源期刊
Current Opinion in Electrochemistry
Current Opinion in Electrochemistry Chemistry-Analytical Chemistry
CiteScore
14.00
自引率
5.90%
发文量
272
审稿时长
73 days
期刊介绍: The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner: 1.The views of experts on current advances in electrochemistry in a clear and readable form. 2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications. In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle: • Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •
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