Esterification reaction of oleic acid catalyzed by modified mesoporous silica SBA-15

D. Pečar, Vladan Mićić, A. Goršek
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Abstract

The esterification reaction of oleic acid with methanol practically does not occur at the temperature of most current industrial processes. If you raise the temperature, significant conversion occurs only above 200°C and after several hours. For the above reasons, all of today's industrial oleic acid esterification technologies are based on catalyzed esterification. Catalysts based on silicates are often used as catalysts in the mentioned reactions because they are cheap, easy to synthesize, insoluble in most organic solvents, and recyclable. In this work, modified mesopo-rous silica SBA-15 was used, which is suitable for a wide range of organic reactions. The effect of the amount of this catalyst on the yield of the esterification reaction was studied. It has been shown that with an increase in the amount of catalyst, the degree of conversion, i.e. the yield of methyl oleate, increases.
改性介孔二氧化硅 SBA-15 催化的油酸酯化反应
油酸与甲醇的酯化反应在目前大多数工业流程的温度下几乎不会发生。如果提高温度,只有在 200°C 以上并经过数小时后才会发生明显的转化。基于上述原因,当今所有的油酸酯化工业技术都是基于催化酯化技术。基于硅酸盐的催化剂通常被用作上述反应的催化剂,因为它们价格便宜、易于合成、不溶于大多数有机溶剂且可回收利用。本研究中使用的是改性介质硅 SBA-15,它适用于多种有机反应。研究了这种催化剂的用量对酯化反应产率的影响。结果表明,随着催化剂用量的增加,转化率(即油酸甲酯的产率)也随之增加。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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