Potentially Harmful Elements Content in Soil and Stream Sediments in Southwestern Districts of Katowice (Southern Poland) – Geochemical Record of Historical Industrial Plants’ Activity

Abstract

The aim of the research was to assess the quality of topsoils and stream sediments in the districts of the Katowice City of southern Poland in the Upper Silesian Industrial Agglomeration, influenced primarily by the exploitation of hard coal deposits and metallurgy. The task was carried out using indicators used to assess anthropogenic soil contamination (contamination factor CF and the Igeo geoaccumulation index), as well as ecotoxicological indicators used to determine the quality of stream sediments (Threshold Effect Concentration TEC and Probable Effect Concentration PEC). In order to indicate the most polluted areas, geochemical maps of selected elements in soil and stream sediments were developed. The material comes from the top layer of soil (0.0–0.3 m) and stream sediments located in the districts of the Katowice City. The work took into account selected potentially harmful elements (PHEs). The concentrations of elements were measured using the ICP-AES method, except for Hg (the CV-AAS method). The values of the CF and Igeo indicators allowed for the indication of high concentrations of most metals, arsenic, and sulfur in the topsoil layer, significantly exceeding the geochemical background values caused by the historical exploitation of Zn-Pb and zinc ores and ferrous metallurgy. The values of the TEC and PEC indicators classify the sediments into categories that may threaten the environment and living organisms.