Synthesis and Property of 2,2-Difluoro-1,4-diazaborole

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-04-23 DOI:10.1093/chemle/upae069

Masataka Nakahara, Yuki Wada, Masaki Kawano, Kengo Hanaya, Takeshi Sugai, Shuhei Higashibayashi

引用次数: 0

Abstract

The synthesis of 2,2-difluoro-1,4-diazaboroles was achieved through the condensation of aliphatic acyltrifluoroborates and amino-N-heteroarenes under acidic conditions. Various N-heteroarenes, including pyridine, pyrimidine, pyridazine, thiazole, and isoquinoline, were successfully employed in the reaction. Among the synthesized 2,2-difluoro-1,4-diazaboroles, the one with an isoquinoline structure exhibited the most intense light blue emission.

查看原文本刊更多论文

2,2-Difluoro-1,4-diazaborole 的合成与性质

在酸性条件下，通过脂肪族酰基三氟硼酸盐和氨基-N-庚烯的缩合，合成了 2,2-二氟-1,4-二氮杂硼烷。反应中成功地使用了多种 N-己烯，包括吡啶、嘧啶、哒嗪、噻唑和异喹啉。在合成的 2,2-二氟-1,4-二氮杂硼烷中，具有异喹啉结构的硼烷发出的淡蓝色光最强烈。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.