K-core attack, equilibrium K-core, and kinetically constrained spin system

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Hai-Jun Zhou
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引用次数: 0

Abstract

Kinetically constrained spin systems are toy models of supercooled liquids and amorphous solids. In this Perspective, we revisit the prototypical Fredrickson-Andersen (FA) kinetically constrained model from the viewpoint of K-core combinatorial optimization. Each kinetic cluster of the FA system, containing all the mutually visitable microscopic occupation configurations, is exactly the solution space of a specific instance of the K-core attack problem. The whole set of different jammed occupation patterns of the FA system is the configuration space of an equilibrium K-core problem. Based on recent theoretical results achieved on the K-core attack and equilibrium K-core problems, we discuss the thermodynamic spin glass phase transitions and the maximum occupation density of the fully unfrozen FA kinetic cluster, and the minimum occupation density and extreme vulnerability of the partially frozen (jammed) kinetic clusters. The equivalence between K-core attack and the fully unfrozen FA kinetic cluster also implies a new way of sampling K-core attack solutions.
K 核攻击、平衡 K 核和动力学约束自旋系统
动力学约束自旋系统是过冷液体和无定形固体的玩具模型。在本《视角》中,我们从 K 核组合优化的角度重新审视了原型弗雷德里克森-安德森(Fredrickson-Andersen,FA)动力学约束模型。FA 系统的每个动力学簇包含所有可相互访问的微观占位配置,正是 K 核攻击问题特定实例的解空间。整个 FA 系统的不同干扰占据模式集合就是均衡 K 核问题的配置空间。基于最近在 K 核攻击和平衡 K 核问题上取得的理论成果,我们讨论了完全解冻的 FA 动力簇的热力学自旋玻璃相变和最大占据密度,以及部分冻结(卡住)的动力簇的最小占据密度和极端脆弱性。K 核攻击与完全解冻的 FA 动力簇之间的等价关系也意味着一种新的 K 核攻击解决方案采样方法。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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