Densities, Excess Molar Volumes and Excess Refractive Indices for Binary Solutions of D2O and H2O

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-04-24 DOI:10.1007/s10953-024-01377-5

Shekhar Kumar

引用次数: 0

Abstract

Heavy water is an important industrial chemical for nuclear power generation from natural uranium, precursor for tritium, required for fusion power generation and an important chemical and biochemical tracer. Its separation from natural or synthetic D₂O–H₂O binary solutions is highly energy intensive. Therefore for development of chemical and physiochemical processes for its separation, physical properties of binary solutions of D₂O and H₂O are important. In this study, density, excess molar volume, refractive indices and related properties are reported for D₂O–H₂O binary solutions.

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D2O 和 H2O 二元溶液的密度、过量摩尔体积和过量折射率

重水是一种重要的工业化学品，用于利用天然铀进行核能发电，是核聚变发电所需的氚的前体，也是一种重要的化学和生物化学示踪剂。从天然或合成的 D2O-H2O 二元溶液中分离重水需要耗费大量能源。因此，要开发用于分离氚的化学和物理化学过程，D2O 和 H2O 二元溶液的物理特性非常重要。本研究报告了 D2O-H2O 二元溶液的密度、过量摩尔体积、折射率和相关性质。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.