{"title":"Stochastic Equilibrium Analysis to Optimize Solid Propellant Combustion Gas Composition","authors":"Quentin Michalski, Adrian Pudsey","doi":"10.2514/1.b39318","DOIUrl":null,"url":null,"abstract":"Solid fuel ducted rockets operate with two-stage combustion. The first stage generates burnt products from the combustion of a fuel-rich solid propellant. In the second stage, those combustion products react with air and are ejected through a nozzle to produce thrust. The combustion efficiency of such a device strongly influences its performance and depends on the composition of the rich-fuel-burnt pyrolysis products. This study investigates the sensitivity of carbon, hydrogen, oxygen, and nitrogen (CHON) solid fuels’ burnt product composition to the fuel properties, composition, and heat of formation. The calculations are performed assuming adiabatic, isobaric chemical equilibrium on synthetic species. Existing species’ properties constrain the properties of the synthetic species. The trends of formation of the main species observed in gas generators, i.e., [Formula: see text], [Formula: see text], CO, [Formula: see text], [Formula: see text], [Formula: see text], and solid carbon, are presented. The sensitivity of the molar concentration ratio [Formula: see text] of [Formula: see text] to [Formula: see text] to the oxygen balance and propulsive properties is compared with an example of gas generator propellants. Recommendations for the possible optimization of fuel composition are formulated. For blends of the existing CHON species reported in the literature, it is shown that improving [Formula: see text] is only possible by degrading the specific impulse.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"18 1","pages":""},"PeriodicalIF":16.4000,"publicationDate":"2024-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.2514/1.b39318","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Solid fuel ducted rockets operate with two-stage combustion. The first stage generates burnt products from the combustion of a fuel-rich solid propellant. In the second stage, those combustion products react with air and are ejected through a nozzle to produce thrust. The combustion efficiency of such a device strongly influences its performance and depends on the composition of the rich-fuel-burnt pyrolysis products. This study investigates the sensitivity of carbon, hydrogen, oxygen, and nitrogen (CHON) solid fuels’ burnt product composition to the fuel properties, composition, and heat of formation. The calculations are performed assuming adiabatic, isobaric chemical equilibrium on synthetic species. Existing species’ properties constrain the properties of the synthetic species. The trends of formation of the main species observed in gas generators, i.e., [Formula: see text], [Formula: see text], CO, [Formula: see text], [Formula: see text], [Formula: see text], and solid carbon, are presented. The sensitivity of the molar concentration ratio [Formula: see text] of [Formula: see text] to [Formula: see text] to the oxygen balance and propulsive properties is compared with an example of gas generator propellants. Recommendations for the possible optimization of fuel composition are formulated. For blends of the existing CHON species reported in the literature, it is shown that improving [Formula: see text] is only possible by degrading the specific impulse.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.