Experimental Studies of Power-Saturated Spin Modes of Nitroxides in Liquids 1

IF 1.1 4区物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL

Applied Magnetic Resonance Pub Date : 2024-04-19 DOI:10.1007/s00723-024-01651-1

Barney L. Bales, Miroslav Peric, Robert N. Schwartz

引用次数: 0

Abstract

In recent years, the theory of the effect of saturation of EPR spectra of free radicals undergoing spin exchange has been extended to spin exchange frequencies where “peculiar” behavior occurs. In a paper by Salikhov (Appl. Magn. Reson. (2021) 52:1063–1091), analytic expressions were developed that predict the dependence of measurable EPR parameters on the exchange frequencies and the microwave field strength. This work is an experimental test of that theory where, in principle, there are no adjustable parameters.

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液体中氮氧化物功率饱和自旋模式的实验研究 1

近年来，关于发生自旋交换的自由基的 EPR 光谱饱和效应的理论已扩展到发生 "奇特 "行为的自旋交换频率。在萨利霍夫（Salikhov）的一篇论文（Appl.Reson.(2021) 52:1063-1091）中，建立了分析表达式，预测了可测量的 EPR 参数对交换频率和微波场强的依赖性。这项工作是对该理论的实验测试，原则上不存在可调整的参数。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Applied Magnetic Resonance 物理-光谱学

CiteScore

1.90

自引率

10.00%

发文量

审稿时长

2.3 months

期刊介绍： Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.