Research on the sustainable effect of ZnS and MoS 2 decorated biochar nanocomposites for removing quinolones from antibiotic-polluted aqueous solutions

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Australian Journal of Chemistry Pub Date : 2024-04-03 DOI:10.1071/ch23170

Ying-Jie Gan, Yue-hui Wang, Ya-ru Dang, Wen-jie Hao, Zheng-rong Hu, Zhi-wei Zhang, Yu-min Luo, Yan-bo Wu, Ai-jun Song, Zhong-bao Zhao

{"title":"Research on the sustainable effect of ZnS and MoS 2 decorated biochar nanocomposites for removing quinolones from antibiotic-polluted aqueous solutions","authors":"Ying-Jie Gan, Yue-hui Wang, Ya-ru Dang, Wen-jie Hao, Zheng-rong Hu, Zhi-wei Zhang, Yu-min Luo, Yan-bo Wu, Ai-jun Song, Zhong-bao Zhao","doi":"10.1071/ch23170","DOIUrl":null,"url":null,"abstract":"Antibiotic concentrations in wastewater generated by industries such as sewage treatment plants, medical pharmaceuticals and aquaculture has exceeded acceptable levels. It is particularly urgent to seek a method that can efficiently remove antibiotics. The removal potential of three quinolone antibiotics, pefloxacin (PF), levofloxacin (LF) and norfloxacin (NF), in simulated contaminated water was studied using a biochar-based nanomaterial prepared by a hydrothermal method. The data were fitted with adsorption kinetics, isotherms and thermodynamics. The results showed that ZnS–MoS2 activated biochar (ZMMBC) acheived maximum adsorption amounts of 199.42, 125.00 and 142.58 mg g–1 for PF, LF and NF, suggesting that ZMMBC has excellent adsorption performance. The adsorption mechanisms of PF, LF and NF molecules on ZMMBC include complexation, pore filling, π–π interactions, electrostatic interactions and hydrogen bond interactions.","PeriodicalId":8575,"journal":{"name":"Australian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Australian Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1071/ch23170","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Antibiotic concentrations in wastewater generated by industries such as sewage treatment plants, medical pharmaceuticals and aquaculture has exceeded acceptable levels. It is particularly urgent to seek a method that can efficiently remove antibiotics. The removal potential of three quinolone antibiotics, pefloxacin (PF), levofloxacin (LF) and norfloxacin (NF), in simulated contaminated water was studied using a biochar-based nanomaterial prepared by a hydrothermal method. The data were fitted with adsorption kinetics, isotherms and thermodynamics. The results showed that ZnS–MoS₂ activated biochar (ZMMBC) acheived maximum adsorption amounts of 199.42, 125.00 and 142.58 mg g^–1 for PF, LF and NF, suggesting that ZMMBC has excellent adsorption performance. The adsorption mechanisms of PF, LF and NF molecules on ZMMBC include complexation, pore filling, π–π interactions, electrostatic interactions and hydrogen bond interactions.

查看原文本刊更多论文

ZnS 和 MoS 2 装饰生物炭纳米复合材料去除抗生素污染水溶液中喹诺酮类药物的可持续效果研究

污水处理厂、医疗制药和水产养殖等行业产生的废水中的抗生素浓度已超过可接受的水平。寻找一种能有效去除抗生素的方法尤为迫切。通过水热法制备的生物炭基纳米材料研究了模拟污染水中三种喹诺酮类抗生素--培氟沙星（PF）、左氧氟沙星（LF）和诺氟沙星（NF）的去除潜力。采用吸附动力学、等温线和热力学对数据进行了拟合。结果表明，ZnS-MoS2 活性生物炭（ZMMBC）对 PF、LF 和 NF 的最大吸附量分别为 199.42、125.00 和 142.58 mg g-1，表明 ZMMBC 具有优异的吸附性能。PF、LF 和 NF 分子在 ZMMBC 上的吸附机理包括络合、孔隙填充、π-π 相互作用、静电作用和氢键作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Australian Journal of Chemistry 化学-化学综合

CiteScore

2.50

自引率

0.00%

发文量

审稿时长

1.3 months

期刊介绍： Australian Journal of Chemistry - an International Journal for Chemical Science publishes research papers from all fields of chemical science. Papers that are multidisciplinary or address new or emerging areas of chemistry are particularly encouraged. Thus, the scope is dynamic. It includes (but is not limited to) synthesis, structure, new materials, macromolecules and polymers, supramolecular chemistry, analytical and environmental chemistry, natural products, biological and medicinal chemistry, nanotechnology, and surface chemistry. Australian Journal of Chemistry is published with the endorsement of the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and the Australian Academy of Science.