Synthesis and characterization of ordered mesoporous carbon-based materials for electrochemical detection of environmental pollutants

IF 11.1 2区 化学 Q1 CHEMISTRY, ANALYTICAL
Amira Gaber , Selva Bilge , Duygu Bayramoğlu , Yusuf Osman Donar , Ali Sınağ
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引用次数: 0

Abstract

Pesticides, employed in agriculture to boost harvests and control pests, harm the ecosystem. Surface runoff from their widespread use pollutes water and soil. Pesticides deplete beneficial insect populations, upset ecological equilibrium, and contaminate food chains, posing health concerns through bioaccumulation and biomagnification. Moreover, heavy metals from industry, mining, and inappropriate waste disposal are persistent, harmful environmental pollutants. Lead, mercury, cadmium, and arsenic in soils and sediments pollute water supplies and endanger aquatic life, wildlife, and humans. Heavy metal exposure can cause neurological issues, reproductive abnormalities, and cancer, making cleanup necessary. Also, industrial activities, wastewater discharge, and agricultural runoff produce phenolic compounds, another harmful environmental contaminant. Bisphenol A, phenol, and chlorophenols poison aquatic species, limit plant photosynthesis, and alter microbial populations. Additionally, phenolic chemicals can stay in the environment for lengthy durations, causing long-term ecological damage and health concerns from tainted drinking water and food. As a result, environmental monitoring is becoming increasingly important for sensitively detecting and quantifying pesticides, phenolic compounds, and heavy metals. Electrochemical sensors and modification materials are prepared for specific pollutant detection, providing selectivity and sensitivity, thus enabling the detection of the target molecule down to the nanomolar or even picomolar range. In this respect, ordered mesoporous carbon (OMC) materials attract attention in electrochemical sensing applications due to their numerous advantages. OMCs are promising for catalysis and sensing applications due to their well-ordered pore structure, high specific surface area, and tunable pore sizes in the mesopore range. The unique properties of these materials could open a new approach to studying the electrochemical determination of other environmental pollutants. This review covers the properties, advantages, synthesis procedures, and characterization processes of OMCs and focuses on the role of OMCs in the electrochemical detection of environmental pollutants. Moreover, this study examines OMC-based research carried out in recent years in depth.

Abstract Image

用于电化学检测环境污染物的有序介孔碳基材料的合成与表征
农业中使用杀虫剂来提高收成和控制害虫,但却会危害生态系统。广泛使用杀虫剂所产生的地表径流污染了水和土壤。杀虫剂消耗益虫种群,破坏生态平衡,污染食物链,通过生物累积和生物放大作用造成健康问题。此外,工业、采矿业和不恰当的废物处理所产生的重金属也是持久、有害的环境污染物。土壤和沉积物中的铅、汞、镉和砷会污染水源,危及水生生物、野生动物和人类。接触重金属会导致神经系统问题、生殖系统异常和癌症,因此有必要进行清理。此外,工业活动、废水排放和农业径流会产生酚类化合物,这是另一种有害的环境污染物。双酚 A、苯酚和氯酚会毒害水生物种,限制植物的光合作用,并改变微生物种群。此外,酚类化学物质会在环境中长期存留,对生态环境造成长期破坏,并污染饮用水和食物,影响人们的健康。因此,环境监测对于灵敏地检测和量化农药、酚类化合物和重金属变得越来越重要。为检测特定污染物而制备的电化学传感器和改性材料具有选择性和灵敏度高的特点,因此能够检测到纳摩尔甚至皮摩尔范围内的目标分子。在这方面,有序介孔碳(OMC)材料因其众多优点而在电化学传感应用中备受关注。有序介孔碳具有有序的孔隙结构、高比表面积以及在介孔范围内可调的孔隙尺寸,因此在催化和传感应用中大有可为。这些材料的独特性质可为研究其他环境污染物的电化学测定开辟一条新途径。本综述介绍了 OMC 的特性、优势、合成程序和表征过程,并重点探讨了 OMC 在环境污染物电化学检测中的作用。此外,本研究还深入探讨了近年来开展的基于 OMC 的研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Trends in Environmental Analytical Chemistry
Trends in Environmental Analytical Chemistry Chemistry-Analytical Chemistry
CiteScore
21.20
自引率
2.70%
发文量
34
审稿时长
44 days
期刊介绍: Trends in Environmental Analytical Chemistry is an authoritative journal that focuses on the dynamic field of environmental analytical chemistry. It aims to deliver concise yet insightful overviews of the latest advancements in this field. By acquiring high-quality chemical data and effectively interpreting it, we can deepen our understanding of the environment. TrEAC is committed to keeping up with the fast-paced nature of environmental analytical chemistry by providing timely coverage of innovative analytical methods used in studying environmentally relevant substances and addressing related issues.
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