Performance characterization of plywood panels bonded with melamine-urea-formaldehyde resin and cellulose nanofibril/borax as an additive

Mert Yildirim, Zeki Candan, Turgay Akbulut, Douglas Gardner, Stephen Shaler
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Abstract

In this study, different loading levels of cellulose nanofibril and borax were added as reinforcement in melamine-urea-formaldehyde adhesive to enhance the performance properties of plywood panels as engineered wood composites. Physical properties (density, thickness swelling, water absorption, and moisture content), mechanical properties (modulus of rupture, modulus of elasticity, and bonding strength), and formaldehyde content were tested using relevant standards. The results showed that cellulose nanofibril and borax had a synergistic effect, resulting in improved physico-mechanical properties. The best results were obtained by combining 3 % cellulose nanofibril and borax. It was determined that the combination of cellulose nanofibril and borax reinforcement resulted in a significant improvement of around 15 % in the thickness swelling, water absorption, and moisture content of plywood panels. The combination of cellulose nanofibril and borax reinforcing resulted in a significant increase of around 26 % in the modulus of rupture and modulus of elasticity of plywood panels, with a bonding strength of around 47 %. The reinforcement technique did result in a 34 % decrease in free formaldehyde content. As a consequence, cellulose nanofibril and borax can be used as effective additives in the production of plywood panels to enhance their performance properties.
用三聚氰胺-脲醛树脂和纳米纤维素/硼砂作为添加剂粘合的胶合板的性能表征
本研究在三聚氰胺-尿素-甲醛胶粘剂中添加了不同含量的纳米纤维素和硼砂作为增强材料,以提高胶合板作为工程木质复合材料的性能。采用相关标准对物理特性(密度、厚度膨胀率、吸水率和含水率)、机械特性(断裂模数、弹性模量和粘合强度)和甲醛含量进行了测试。结果表明,纳米纤维素和硼砂具有协同作用,从而改善了物理机械性能。将 3 % 的纳米纤维素和硼砂结合使用可获得最佳效果。据测定,将纳米纤维素和硼砂加固结合在一起可显著改善胶合板的厚度膨胀、吸水性和含水率,改善幅度约为 15%。结合使用纳米纤维素和硼砂加固技术,胶合板的断裂模量和弹性模量显著提高了约 26%,粘合强度提高了约 47%。这种加固技术确实使游离甲醛含量降低了 34%。因此,纳米纤维素和硼砂可作为有效的添加剂用于胶合板的生产,以提高其性能特性。
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