High-Strength Copper/Silver Alloys Processed by Cold Spraying for DC and Pulsed High Magnetic Fields

IF 2.6 4区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
Simon Tardieu, Hanane Idrir, Christophe Verdy, Olivier Jay, Nelson Ferreira, François Debray, A. Joulain, Christophe Tromas, Ludovic Thilly, F. Lecouturier-Dupouy
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Abstract

High-strength, high-conductivity copper/silver-alloyed materials were prepared by cold-spray (CS) manufacturing. For DC high-field application at room temperature, bulk Cu/Ag (5% vol. Ag) alloys with high mechanical properties and high electrical conductivity can be obtained by CS and post-heat treatments. For pulsed-field application at liquid nitrogen temperature, bulk Cu/Ag (5% vol. Ag) alloys serve as precursors for room-temperature wire drawing. The Cu/Ag-alloyed bulk CS deposit presents a high yield strength of about 510 MPa with a corresponding electrical resistivity of 1.92 µΩ·cm (at 293 K). The Cu/Ag-alloyed wires show a very high ultimate tensile strength (1660 MPa at 77 K or 1370 MPa at 293 K) and low electrical resistivity (1.05 µΩ·cm at 77 K or 2.56 µΩ·cm at 293 K). Microstructural studies via STEM allow us to understand this very high level of mechanical strength. The results evidence that materials developed by CS exhibit very high mechanical properties compared to materials prepared by other routes, due to the high velocity of the deposited particles, which leads to high initial deformation rates and specific microstructural features.
用于直流和脉冲高磁场的冷喷涂处理高强度铜/银合金
通过冷喷(CS)制造工艺制备了高强度、高导电率的铜/银合金材料。对于室温下的直流高场应用,通过冷喷(CS)和后热处理可获得具有高机械性能和高导电率的铜/银(5% vol. Ag)块状合金。对于液氮温度下的脉冲电场应用,块状铜/银(5% vol. Ag)合金可作为室温拉丝的前体。铜/银合金块状 CS 沉积物具有约 510 兆帕的高屈服强度,相应的电阻率为 1.92 µΩ-cm(293 K 时)。铜/银合金丝则显示出极高的极限抗拉强度(77 K 时为 1660 兆帕,293 K 时为 1370 兆帕)和较低的电阻率(77 K 时为 1.05 µΩ-cm ,293 K 时为 2.56 µΩ-cm)。通过 STEM 进行微观结构研究,我们可以了解这种极高的机械强度。研究结果表明,与其他方法制备的材料相比,希尔思制备的材料具有极高的机械性能,这是由于沉积颗粒的高速度导致了较高的初始变形率和特定的微观结构特征。
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来源期刊
Magnetochemistry
Magnetochemistry Chemistry-Chemistry (miscellaneous)
CiteScore
3.90
自引率
11.10%
发文量
145
审稿时长
11 weeks
期刊介绍: Magnetochemistry (ISSN 2312-7481) is a unique international, scientific open access journal on molecular magnetism, the relationship between chemical structure and magnetism and magnetic materials. Magnetochemistry publishes research articles, short communications and reviews. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.
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