{"title":"Microstructure and dielectric properties of low-temperature sintered MgO-based ceramics at millimeter wave and terahertz frequencies","authors":"Haotian Liu, Zheng Liang, Chang Liu, Cheng Liu, Huaiwu Zhang","doi":"10.1142/s2010135x23500339","DOIUrl":null,"url":null,"abstract":"Low-temperature co-fired ceramics (LTCC) applied in millimeter/microwave and terahertz frequencies (5G/6G) have attracted a lot of attention recently. In this study, MgO-based dielectric ceramics were successfully sintered at 950∘C with the sintering aids: x wt.% of LiF fluoride ([Formula: see text], 4, 6, 8, 10) and 0.5[Formula: see text]wt.% of BBSZ (Bi2O3–B2O3–SiO2–ZnO) glass. BBSZ glass was introduced as another sintering aid to facilitate the sintering and densification. Crystalline structure and micro-morphology were investigated and analyzed. Dielectric properties ([Formula: see text], [Formula: see text], [Formula: see text]) at millimeter/microwave and terahertz wave frequencies were also studied. The ionic characteristics of Mg–O bond ([Formula: see text]), the lattice energy (U) and the bond energy (E) were calculated and analyzed. It is suggested that the optimal [Formula: see text], where [Formula: see text], [Formula: see text][Formula: see text]GHz (@12[Formula: see text]GHz) and [Formula: see text][Formula: see text]ppm/∘C at millimeter/microwave range. When the frequency was up to terahertz (1.0[Formula: see text]THz), the [Formula: see text] values were 8.8–9.35 and the tan[Formula: see text] were [Formula: see text]–[Formula: see text]. The experimental results indicated that the low-temperature sintered MgO-based ceramics have potential for millimeter/microwave and terahertz communication applications.","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":"58 4","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2024-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Bio Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1142/s2010135x23500339","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, BIOMATERIALS","Score":null,"Total":0}
引用次数: 0
Abstract
Low-temperature co-fired ceramics (LTCC) applied in millimeter/microwave and terahertz frequencies (5G/6G) have attracted a lot of attention recently. In this study, MgO-based dielectric ceramics were successfully sintered at 950∘C with the sintering aids: x wt.% of LiF fluoride ([Formula: see text], 4, 6, 8, 10) and 0.5[Formula: see text]wt.% of BBSZ (Bi2O3–B2O3–SiO2–ZnO) glass. BBSZ glass was introduced as another sintering aid to facilitate the sintering and densification. Crystalline structure and micro-morphology were investigated and analyzed. Dielectric properties ([Formula: see text], [Formula: see text], [Formula: see text]) at millimeter/microwave and terahertz wave frequencies were also studied. The ionic characteristics of Mg–O bond ([Formula: see text]), the lattice energy (U) and the bond energy (E) were calculated and analyzed. It is suggested that the optimal [Formula: see text], where [Formula: see text], [Formula: see text][Formula: see text]GHz (@12[Formula: see text]GHz) and [Formula: see text][Formula: see text]ppm/∘C at millimeter/microwave range. When the frequency was up to terahertz (1.0[Formula: see text]THz), the [Formula: see text] values were 8.8–9.35 and the tan[Formula: see text] were [Formula: see text]–[Formula: see text]. The experimental results indicated that the low-temperature sintered MgO-based ceramics have potential for millimeter/microwave and terahertz communication applications.
期刊介绍:
ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications.
The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.