Identification of fruit (fruit) distillates and alcoholic beverages based on them

Е.В. Ульянова, Ольга Николаевна Ободеева, В.А. Захарова, И.Г. Соломин
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Abstract

Currently, there is an increase in consumer demand for alcoholic drinks based on fruit distillates, including fruit vodkas. In accordance with current regulatory documentation, fruit vodkas are produced without the addition of any flavors or artificial colors. This allows them to be classified as an elite group of alcoholic products and, at the same time, increases the risk of falsification. Common methods of adulterating fruit vodkas are: complete or partial replacement of fruit ethanol with ethanol of non-fruit origin; introduction of flavoring additives and flavorings; replacement of expensive fruit raw materials with other, cheaper raw materials. In this regard, ensuring the quality and safety of distillates and alcoholic beverages from fruit raw materials and increasing the efficiency of their identification are urgent tasks. he analysis of regulatory documentation and experimental data is devoted to the issues of identifying counterfeit products based on them. The features of the composition of fruit (fruit) distillates and alcoholic drinks from stone fruit raw materials are considered. Approaches to determining their origin and methods of establishing authenticity based on botanical origin are analyzed. It has been shown that products from certain types of fruit stone raw materials can be differentiated by the ratio of the concentrations of the main higher alcohols (1-propanol / sum of isobutanol and isoamylol). It has been established that the value of the indicator 1-propanol/isobutanol+isoamylol practically does not change during product storage and, therefore, can be used as an identification criterion. The presence in certain concentrations of propylene glycol and/or benzyl alcohol and/or triacetin, often used as flavor components, in products may indicate the presence of the latter. Isotope mass spectrometry can also be used to determine the presence of non-fruit alcohols. The possibility of using the ratio of optical isomers of individual volatile chiral compounds, including terpenes, as an additional criterion for differentiating distillates from fruit stone raw materials was noted. It has been shown that to identify distillates from dogwood it is possible to use specific marker compounds – decanal, methyl (Z)-9-octadecenoate, -cadinene.
水果(果实)蒸馏物和酒精饮料的鉴定
目前,消费者对以水果蒸馏物为基础的酒精饮料(包括水果伏特加)的需求不断增加。根据现行法规文件,水果伏特加在生产过程中不添加任何香精或人工色素。这使得水果伏特加被归类为精英酒类产品,同时也增加了掺假的风险。水果伏特加掺假的常见方法有:用非水果来源的乙醇完全或部分替代水果乙醇;引入调味添加剂和香料;用其他更便宜的原料替代昂贵的水果原料。在这方面,确保水果原料蒸馏物和酒精饮料的质量和安全以及提高其鉴别效率是当务之急。考虑了水果(果实)蒸馏物和核果原料酒精饮料的成分特点。分析了确定其原产地的方法和根据植物原产地确定真伪的方法。研究表明,可以通过主要高级醇类(1-丙醇/异丁醇和异戊醇之和)的浓度比来区分某些类型的核果原料产品。经证实,1-丙醇/异丁醇+异戊醇的指标值在产品储存过程中几乎不会发生变化,因此可用作鉴别标准。如果产品中含有一定浓度的丙二醇和/或苯甲醇和/或三醋精(通常用作香料成分),则表明产品中含有后者。同位素质谱法也可用于确定非果酒醇的存在。还有人指出,可以使用单个挥发性手性化合物(包括萜烯)的光学异构体比率作为区分来自果核原料的蒸馏物的额外标准。研究表明,可以使用特定的标记化合物--癸醛、(Z)-9-十八烯酸甲酯、-cadinene 来鉴别山茱萸蒸馏物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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