Elemental Aspects of Transition Metals Pertinent to Organometallic Chemistry: Properties, Periodicity, Curiosities, and Related Main Group Issues

IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2024-03-29 DOI:10.1021/acs.organomet.3c00529

Peter T. Wolczanski*,

引用次数: 0

Abstract

This tutorial on transition metal chemistry─sans the lanthanides and actinides─is intended as preliminary information for a high-level undergraduate (UG) inorganic, organometallics, or a comparable first-year graduate (G) course. It features ionization energies (IEs) and comparative nd and (n+1)s orbital energies, electron affinities (EAs), electronegativities (ENs), and covalent radii (c_r). Redox properties of appropriate aquo complexes (ΔE°_red = E°(red)) are also included due to their impact on critical properties and reactivity, as are pertinent aspects of the main group elements.

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与有机金属化学有关的过渡金属元素方面：性质、周期性、奇异性和相关主族问题

这本过渡金属化学教程（不包括镧系元素和锕系元素）旨在为高年级本科生（UG）无机、有机金属学或类似的研究生一年级课程提供初步信息。它包括电离能 (IEs) 和 nd 和 (n+1)s 轨道能、电子亲和力 (EAs)、电负性 (ENs) 和共价半径 (cr) 的比较。由于适当水络合物的氧化还原特性（ΔE°red = E°(red)）对临界特性和反应性的影响，因此也包括在内，主族元素的相关方面也是如此。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.