Efficient preparation strategy of high quantum yield multicolor CDs for warm white LED

Abstract

Multicolor carbon dots (CDs) possess tremendous potential applications, especially in optoelectronic devices. However, further applications in warm white LED have been constrained due to the extremely low quantum yield (QY) of multicolor CDs. In this work, fluorescence enhancement multicolor CDs (o-CDs(cat.) (emitted yellow, Em = 550 nm, QY = 85.4 %), m-CDs(cat.) (emitted blue, Em = 440 nm, QY = 35.7 %), p-CDs(cat.) (emitted red, Em = 610 nm, QY = 73.8 %)) with almost 15 % QY improvement, without changing the fluorescence emission wavelength, was successfully achieved by introducing MnSO₄ into the reaction system. The relevant mechanism may be the catalytic effect of MnSO₄, which leads to the increased content of C = N and pyridine N, further suppressing non radiative transitions, leading to the increasement of QY. Finally, the obtained high QY multicolor CDs were applied to warm white LED with the color coordinates (CIE) of (0.33,0.36), color rendering index (CRI) of 90, correlated color temperature (CCT) of 3473 K. Laying the foundation for the research methods and mechanisms of metal ion caused high QY of CDs.