N-(2-Aminobenzoyl)benzotriazole Mediated Synthesis of 3-Acyl-2-alkyl(aryl)-4-hydroxyquinolines and 3-Acylamino-4(3H) quinazolinones.

IF 1.3 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Turkish Journal of Chemistry Pub Date : 2023-10-16 eCollection Date: 2024-01-01 DOI:10.55730/1300-0527.3642

İlbilge Merve Şenol, Sevtem Gökbulut Satioğlu, İlhami Çelik

引用次数: 0

Abstract

New methods have been developed for the synthesis of the substituted quinolines and quinazolinones derivatives by utilizing N-(2-aminobenzoyl)benzotriazoles under mild reaction conditions. 3-Acyl-2-alkyl(aryl)-4-hydroxyquinolines were obtained in modarete yields by the reaction of N-(2-aminobenzoyl)benzotriazoles and diketones in the presence of tert-BuOK. 3-Acylamino-4(3H) quinazolinones were obtained in good yields via N-(2-aminobenzoyl)benzotriazoles, orthoester and hyrazides in one-pot.

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N-(2-氨基苯甲酰基)苯并三唑介导的 3-酰基-2-烷基(芳基)-4-羟基喹啉和 3-酰氨基-4(3H)喹唑啉酮的合成。

利用 N-(2-氨基苯甲酰基)苯并三唑在温和的反应条件下合成取代的喹啉和喹唑啉酮衍生物的新方法已经开发出来。在叔丁氧钾存在下，N-(2-氨基苯甲酰基)苯并三唑和二酮反应得到 3-酰基-2-烷基(芳基)-4-羟基喹啉，产率为模数。通过 N-(2-氨基苯甲酰基)苯并三唑、正酯和酰肼，以一锅法获得了 3-酰氨基-4(3H)喹唑啉酮，收率很高。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Turkish Journal of Chemistry 化学-工程：化工

CiteScore

2.40

自引率

7.10%

发文量

审稿时长

3 months

期刊介绍： The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.