New Flavonoids of the Genus Scutellaria. II. Baicalein and Wogonin Glycosides from S. baicalensis

IF 0.8 4区 化学 Q4 CHEMISTRY, MEDICINAL
D. N. Olennikov, N. K. Chirikova
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引用次数: 0

Abstract

New glycosides of baicalein (1–4) and wogonin (5 and 6) were found by studying phenolic compounds from roots of Scutellaria baicalensis Georgi (Lamiaceae) grown with treatment by 24-epibrassinolide. The new compounds were baicalein 7-O-(2′′-O-β-D-glucosyl)-β-D-glucuronopyranoside (scutellariside III, 1), baicalein 6-O-β-D-glucopyranoside-7-O-(2′′-O-β-D-glucosyl)-β-D-glucoronopyranoside (scutellariside IV, 2), baicalein 6-O-β-D-glycopyranosyl-7-O-β-D-glucuronopyranoside (scutellariside V, 3), baicalein 7-O-(2′′-O-malonyl)-β-D-glucuronopyranoside (scutellariside VI, 4), wogonin 7-O-(2′′-O-β-D-glucosyl)-β-D-glucuronopyranoside (scutellariside VII, 5), and wogonin 7-O-(2′′-O-malonyl)-β-D-glucuronopyranoside (scutellariside VIII, 5) according to UV and NMR spectroscopic and mass spectrometric data.

黄芩属的新黄酮类化合物。II.黄芩中的黄芩素和黄芩苷
通过研究经 24-epibrassinolide 处理的黄芩根中的酚类化合物,发现了新的黄芩苷(1-4)和黄芩素(5 和 6)。新化合物为黄芩苷 7-O-(2′′-O-β-D-葡萄糖基)-β-D-葡萄糖醛酸吡喃糖苷(黄芩苷 III,1)、黄芩素 6-O-β-D-吡喃葡萄糖苷-7-O-(2′′-O-β-D-吡喃葡萄糖基)-β-D-吡喃葡萄糖呋喃糖苷(黄芩苷 IV,2),黄芩素 6-O-β-D-吡喃葡萄糖基-7-O-β-D-吡喃葡萄糖呋喃糖苷(黄芩苷 V,3)、黄芩苷 7-O-(2′′-O-丙二酰基)-β-D-吡喃葡萄糖呋喃糖苷(黄芩苷 VI,4)、黄芩素 7-O-(2′′-O-β-D-吡喃葡萄糖基)-β-D-吡喃葡萄糖呋喃糖苷(黄芩苷 VII、5)和沃戈宁 7-O-(2′′-O-丙二酰基)-β-D-吡喃葡萄糖呋喃糖苷(黄芩苷 VIII,5)。
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来源期刊
Chemistry of Natural Compounds
Chemistry of Natural Compounds 化学-有机化学
CiteScore
1.40
自引率
25.00%
发文量
265
审稿时长
7.8 months
期刊介绍: Chemistry of Natural Compounds publishes reviews and general articles about the structure of different classes of natural compounds, the chemical characteristics of botanical families, genus, and species, to establish the comparative laws and connection between physiological activity and the structure of substances.
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