Adsorption and separation technologies based on supramolecular macrocycles for water treatment

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引用次数: 0

Abstract

The escalating challenges in water treatment, exacerbated by climate change, have catalyzed the emergence of innovative solutions. Novel adsorption separation and membrane filtration methodologies, achieved through molecular structure manipulation, are gaining traction in the environmental and energy sectors. Separation technologies, integral to both the chemical industry and everyday life, encompass concentration and purification processes. Macrocycles, recognized as porous materials, have been prevalent in water treatment due to their inherent benefits: stability, adaptability, and facile modification. These structures typically exhibit high selectivity and reversibility for specific ions or molecules, enhancing their efficacy in water purification processes. The progression of purification methods utilizing macrocyclic frameworks holds promise for improved adsorption separations, membrane filtrations, resource utilization, and broader water treatment applications. This review encapsulates the latest breakthroughs in macrocyclic host-guest chemistry, with a focus on adsorptive and membrane separations. The aim is to spotlight strategies for optimizing macrocycle designs and their subsequent implementation in environmental and energy endeavors, including desalination, elemental extraction, seawater energy harnessing, and sustainable extraction. Hopefully, this review can guide the design and functionality of macrocycles, offering a significantly promising pathway for pollutant removal and resource utilization.

基于超分子大环的水处理吸附和分离技术
气候变化加剧了水处理方面不断升级的挑战,催化了创新解决方案的出现。通过分子结构操作实现的新型吸附分离和膜过滤方法在环境和能源领域正日益受到重视。分离技术是化学工业和日常生活不可或缺的组成部分,包括浓缩和提纯过程。被视为多孔材料的大环由于其固有的优点:稳定性、适应性和易于改性,在水处理领域非常普遍。这些结构通常对特定离子或分子具有高选择性和可逆性,从而提高了它们在水净化过程中的功效。利用大环框架的净化方法的发展为改进吸附分离、膜过滤、资源利用和更广泛的水处理应用带来了希望。本综述囊括了大环主客体化学的最新突破,重点关注吸附分离和膜分离。目的是重点介绍优化大环设计的策略,以及随后在环境和能源领域的应用,包括海水淡化、元素提取、海水能源利用和可持续提取。希望这篇综述能够为大循环的设计和功能提供指导,为污染物去除和资源利用提供一条大有可为的途径。
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来源期刊
Eco-Environment & Health
Eco-Environment & Health 环境科学与生态学-生态、环境与健康
CiteScore
11.00
自引率
0.00%
发文量
18
审稿时长
22 days
期刊介绍: Eco-Environment & Health (EEH) is an international and multidisciplinary peer-reviewed journal designed for publications on the frontiers of the ecology, environment and health as well as their related disciplines. EEH focuses on the concept of “One Health” to promote green and sustainable development, dealing with the interactions among ecology, environment and health, and the underlying mechanisms and interventions. Our mission is to be one of the most important flagship journals in the field of environmental health. Scopes EEH covers a variety of research areas, including but not limited to ecology and biodiversity conservation, environmental behaviors and bioprocesses of emerging contaminants, human exposure and health effects, and evaluation, management and regulation of environmental risks. The key topics of EEH include: 1) Ecology and Biodiversity Conservation Biodiversity Ecological restoration Ecological safety Protected area 2) Environmental and Biological Fate of Emerging Contaminants Environmental behaviors Environmental processes Environmental microbiology 3) Human Exposure and Health Effects Environmental toxicology Environmental epidemiology Environmental health risk Food safety 4) Evaluation, Management and Regulation of Environmental Risks Chemical safety Environmental policy Health policy Health economics Environmental remediation
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