Determination of Naphthalene Concentration in Honey a New Method using by HS-GC/MS (Headspace-Gas Chromatography/Mass Spectrometry)

E. Izol
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Abstract

Honey is seen by people as a very significant food. It is included in diets and used for the treatment of many diseases. However, contamination of honey, which is a source of healing, with harmful components from the outside makes honey harmful. Pesticides are known to be detected in honey. These pests are transmitted to honey by environmental conditions or incorrect beekeeping practices. Naphthalene is used by beekeepers to prevent mothballing of honeycombs or honey contaminated with honey due to environmental reasons. Naphthalene, which has carcinogenic properties, also causes different diseases. Therefore, the concentration of naphthalene in honey should not exceed a certain limit. For the determination of this, many different analysis methods are developed and applied. In this study, the naphthalene concentration of honey from Bingöl province and its districts, one of the important beekeeping centers in Turkey, was determined by a new HS-GC/MS method that does not require sample preparation. No naphthalene concentration was detected in eight different honey samples. The fact that naphthalene concentration was not detected in honeys from Bingöl province indicates that beekeepers do not use naphthalene and that naphthalene is not contaminated by environmental factors.
利用顶空气相色谱/质谱法(HS-GC/MS)测定蜂蜜中萘浓度的新方法
蜂蜜被人们视为一种非常重要的食品。它被列入饮食中,并用于治疗许多疾病。然而,蜂蜜作为治疗疾病的源泉,如果受到外界有害成分的污染,就会对人体造成危害。众所周知,蜂蜜中含有杀虫剂。这些害虫是通过环境条件或不正确的养蜂方法传播到蜂蜜中的。养蜂人使用萘来防止因环境原因造成的蜂窝蛀虫或蜂蜜污染。萘具有致癌特性,也会引发各种疾病。因此,蜂蜜中的萘浓度不应超过一定的限度。为此,人们开发并应用了许多不同的分析方法。在这项研究中,采用一种无需样品制备的 HS-GC/MS 新方法,测定了土耳其重要养蜂中心之一宾格尔省及其各地区蜂蜜中的萘浓度。在八个不同的蜂蜜样品中均未检测到萘浓度。在宾格尔省的蜂蜜中未检测到萘浓度这一事实表明,养蜂人不使用萘,萘也未受到环境因素的污染。
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