Application of Nickel Foam As a Porous Transport Layer in a Anion Exchange Membrane Water Electrolyzer

IF 0.8 Q3 Engineering
I. V. Pushkareva, A. S. Pushkarev, M. A. Solovyev, S. I. Butrim, V. N. Kuleshov, S. V. Kurochkin, N. V. Kuleshov, V. N. Fateev
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Abstract

Тhe efficiency and the performance of membrane electrode assemblies (MEAs) of the anion exchange membrane (AEM) water electrolyzer is determined to a significant degree by the properties of the materials used as porous transport layers (PTLs). Due to the high surface roughness, porosity, and pore size, the direct use of Ni foam as an electrode material is difficult, and its preliminary compression is required, which irreversibly affects the electrode structure. In the presented work, the effect of Ni foam compression on the structure of an electrode based on it, as well as on the AEM water electrolyzer MEA is considered, including the distribution of voltage losses. The effect of the compression degree on the Ni-foam electrode structure and the performance of the AEM water electrolyzer MEA is considered. The optimal electrode compression provides a significant decrease in the loss of microporous layer particles and catalyst layer nanoparticles in deep surface voids of the PTL, and the development of an interface between the nanostructured catalyst layer and the electrode.

Abstract Image

Abstract Image

镍泡沫作为多孔传输层在阴离子交换膜水电解槽中的应用
阴离子交换膜(AEM)水电解槽膜电极组件(MEA)的效率和性能在很大程度上取决于用作多孔传输层(PTL)的材料的特性。由于泡沫镍具有较高的表面粗糙度、孔隙率和孔径,因此很难直接用作电极材料,而且需要对其进行初步压缩,这对电极结构造成了不可逆的影响。在本研究中,考虑了压缩泡沫镍对以其为基础的电极结构以及 AEM 水电解槽 MEA 的影响,包括电压损失的分布。研究还考虑了压缩程度对镍泡沫电极结构和 AEM 水电解槽 MEA 性能的影响。最佳电极压缩度可显著减少 PTL 深表面空隙中微孔层颗粒和催化剂层纳米颗粒的损失,并在纳米结构催化剂层和电极之间形成界面。
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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
自引率
0.00%
发文量
0
期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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