Yu. V. Bilichenko, Pham Van Thuan, D. V. Onuchin, R. S. Borisov, I. B. Sokol’skaya, V. V. Kireev
{"title":"Novel Epoxy-Aryloxy Cyclotriphosphazenes with Reduced Functionality","authors":"Yu. V. Bilichenko, Pham Van Thuan, D. V. Onuchin, R. S. Borisov, I. B. Sokol’skaya, V. V. Kireev","doi":"10.1134/S1560090424600141","DOIUrl":null,"url":null,"abstract":"<p>Mixed hydroxy-aryloxy cyclotriphosphazenes have been synthesized via the interaction of hexachlorocyclotriphosphazene with a mixture of 4-allyl-2-methoxyphenol and diphenylolpropane (molar ratio 3.5 : 7.0). Their subsequent epoxidation with epichlorohydrin has afforded phosphazene-containing oligoepoxides with the phosphazene fraction of 50%. Optimal conditions for the synthesis of the composition-uniform phosphazene-containing oligoepoxides bearing one, two, and three epoxide groups in the phosphazene cycle have been elaborated. Such phosphazene-containing oligoepoxides can be cured with the curing agents common for the epoxy resins, to afford self-extinguishing compositions.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"65 6","pages":"746 - 754"},"PeriodicalIF":1.0000,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090424600141","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Mixed hydroxy-aryloxy cyclotriphosphazenes have been synthesized via the interaction of hexachlorocyclotriphosphazene with a mixture of 4-allyl-2-methoxyphenol and diphenylolpropane (molar ratio 3.5 : 7.0). Their subsequent epoxidation with epichlorohydrin has afforded phosphazene-containing oligoepoxides with the phosphazene fraction of 50%. Optimal conditions for the synthesis of the composition-uniform phosphazene-containing oligoepoxides bearing one, two, and three epoxide groups in the phosphazene cycle have been elaborated. Such phosphazene-containing oligoepoxides can be cured with the curing agents common for the epoxy resins, to afford self-extinguishing compositions.
期刊介绍：
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
