Retrieval of NO2 Tropospheric Column from Ground-Based FTIR Measurements of Direct Solar Radiation

IF 0.9 Q4 OPTICS
M. V. Makarova, D. V. Ionov, H. H. Imkhasin, A. V. Poberovskii, A. V. Polyakov, V. S. Kostsov, B. K. Makarov, S. C. Foka
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引用次数: 0

Abstract

Based on the analysis of high-resolution FTIR spectra recorded at the atmospheric monitoring station of St. Petersburg State University during 2009–2022, a possibility of deriving the NO2 tropospheric column from ground-based measurements of direct solar radiation in the mid-IR range is studied. The best agreement (correlation coefficient r = 0.68) with simultaneous DOAS measurements of the NO2 tropospheric column at the same monitoring station is provided by a retrieval technique based on the use of the spectral range 2914.30–2914.85 cm−1 in combination with the Tikhonov–Phillips regularization. It is shown that FTIR measurements make it possible to reliably detect high levels of tropospheric NO2 at the SPbSU monitoring station. Our results can be used at the FTIR stations of the NDACC network for significant expansion of the geography of tropospheric NO2 monitoring.

Abstract Image

从太阳直射辐射的地基傅立叶变换红外测量数据中读取对流层中的二氧化氮气柱
摘要-- 根据对 2009-2022 年期间圣彼得堡国立大学大气监测站记录的高分辨率傅立叶变换红外光谱的分析,研究了从中红外范围太阳直接辐射地面测量值推导出对流层二氧化氮柱的可能性。基于 2914.30-2914.85 cm-1 光谱范围的检索技术与 Tikhonov-Phillips 正则化相结合,与同一监测站的二氧化氮对流层柱同步 DOAS 测量结果达到了最佳一致(相关系数 r = 0.68)。结果表明,傅立叶变换红外测量能够可靠地检测到 SPbSU 监测站对流层中的高浓度 NO2。我们的结果可用于 NDACC 网络的傅立叶变换红外台站,以显著扩大对流层 NO2 监测的地域范围。
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来源期刊
CiteScore
2.40
自引率
42.90%
发文量
84
期刊介绍: Atmospheric and Oceanic Optics  is an international peer reviewed journal that presents experimental and theoretical articles relevant to a wide range of problems of atmospheric and oceanic optics, ecology, and climate. The journal coverage includes: scattering and transfer of optical waves, spectroscopy of atmospheric gases, turbulent and nonlinear optical phenomena, adaptive optics, remote (ground-based, airborne, and spaceborne) sensing of the atmosphere and the surface, methods for solving of inverse problems, new equipment for optical investigations, development of computer programs and databases for optical studies. Thematic issues are devoted to the studies of atmospheric ozone, adaptive, nonlinear, and coherent optics, regional climate and environmental monitoring, and other subjects.
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