Recent advances in the hybrid cathode for rechargeable zinc-bromine redox batteries

IF 7.9 2区 化学 Q1 CHEMISTRY, PHYSICAL
Dabin Han, Sangaraju Shanmugam
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引用次数: 0

Abstract

Rechargeable metal-bromine batteries have emerged as promising candidates to develop competitive, cost-effective, high-energy-density energy storage systems. The general configuration of a metal-bromine battery includes a metal anode and a bromine cathode. The emergence of zinc-bromine redox batteries (ZBRBs) is attributed to the earth's abundance of zinc, the cost-effectiveness of the active materials, and the high theoretical energy density. Recent advancements have highlighted using bromides (Br, Br2, and Brn (n = 3, 5, 7 …)) entrapping materials for the cathode to enhance the Br/Br2 redox reaction and inhibit the Br2 diffusion in the ZBRBs. This review aims to explore the various arrangements and insights into bromides-entrapping-based cathodes recently reported. Finally, we share perspectives on the remaining challenges and prospects for the ZBRBs.

Abstract Image

可充电锌溴氧化还原电池混合阴极的最新进展
可充电金属溴电池已成为开发具有竞争力、成本效益高、能量密度大的储能系统的理想候选电池。金属溴电池的一般构造包括一个金属阳极和一个溴阴极。锌溴氧化还原电池(ZBRBs)的出现得益于地球上丰富的锌、活性材料的成本效益以及理论上的高能量密度。最近的研究进展突出了使用溴化物(Br、Br 和 Br(n=3、5、7......))夹带材料作为阴极,以增强溴/硼氧化还原反应并抑制溴在 ZBRB 中的扩散。本综述旨在探讨最近报道的基于溴化物诱捕的阴极的各种安排和见解。最后,我们分享了对 ZBRBs 面临的挑战和前景的看法。
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来源期刊
Current Opinion in Electrochemistry
Current Opinion in Electrochemistry Chemistry-Analytical Chemistry
CiteScore
14.00
自引率
5.90%
发文量
272
审稿时长
73 days
期刊介绍: The development of the Current Opinion journals stemmed from the acknowledgment of the growing challenge for specialists to stay abreast of the expanding volume of information within their field. In Current Opinion in Electrochemistry, they help the reader by providing in a systematic manner: 1.The views of experts on current advances in electrochemistry in a clear and readable form. 2.Evaluations of the most interesting papers, annotated by experts, from the great wealth of original publications. In the realm of electrochemistry, the subject is divided into 12 themed sections, with each section undergoing an annual review cycle: • Bioelectrochemistry • Electrocatalysis • Electrochemical Materials and Engineering • Energy Storage: Batteries and Supercapacitors • Energy Transformation • Environmental Electrochemistry • Fundamental & Theoretical Electrochemistry • Innovative Methods in Electrochemistry • Organic & Molecular Electrochemistry • Physical & Nano-Electrochemistry • Sensors & Bio-sensors •
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