Deformation behavior of SmCo compounds via amorphization and recrystallization

IF 5.2 1区 化学 Q1 CHEMISTRY, APPLIED
Wei Quan, Longfei Ma, Yanbai Chen, Niuniu Wang, Hubin Luo, Qiang Zheng, Juan Du
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引用次数: 0

Abstract

In recent years, nanocrystalline magnets based on the critical single domain size theory have received increasing attention. However, nanocrystalline magnets are difficult to enhance the remanent magnetization by forming textures with conventional magnetic field orientation. Texturing of nanocrystalline magnets is usually done using the hot pressing and hot deformation technique, but there are some difficulties in applying this technique to form texture in SmCo systems. To discover and solve the difficulties of obtaining texturized nanocrystalline SmCo-based magnets during the deformation process, samarium cobalt magnets with different degrees of deformation were first experimentally prepared by low strain rate hot deformation method. Then, molecular dynamics simulations were utilized to study the microstructural changes and the multi-phase formation process during hot deformation. The process of deformation together with the reason why it is difficult to form textures in SmCo systems by low-temperature hot deformation is discussed, and the strain energy densities of SmCo multiphase in multiple directions were calculated, which gives a feasible method to form low-temperature hot deformation textures in SmCo systems experimentally.
钐钴化合物通过非晶化和再结晶产生的变形行为
近年来,基于临界单畴尺寸理论的纳米晶磁体受到越来越多的关注。然而,纳米晶磁体很难通过形成具有传统磁场取向的纹理来增强剩磁。纳米晶磁体的纹理形成通常采用热压和热变形技术,但在 SmCo 系统中应用该技术形成纹理存在一些困难。为了发现和解决在变形过程中获得纹理化纳米晶 SmCo 基磁体的困难,首先通过低应变率热变形方法实验制备了不同变形程度的钐钴磁体。然后,利用分子动力学模拟研究了热变形过程中的微观结构变化和多相形成过程。讨论了变形过程以及低温热变形难以在 SmCo 系统中形成纹理的原因,并计算了 SmCo 多相在多个方向上的应变能密度,从而给出了在 SmCo 系统中通过实验形成低温热变形纹理的可行方法。
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来源期刊
Journal of Rare Earths
Journal of Rare Earths 化学-应用化学
CiteScore
8.70
自引率
14.30%
发文量
374
审稿时长
1.7 months
期刊介绍: The Journal of Rare Earths reports studies on the 17 rare earth elements. It is a unique English-language learned journal that publishes works on various aspects of basic theory and applied science in the field of rare earths (RE). The journal accepts original high-quality original research papers and review articles with inventive content, and complete experimental data. It represents high academic standards and new progress in the RE field. Due to the advantage of abundant RE resources of China, the research on RE develops very actively, and papers on the latest progress in this field emerge every year. It is not only an important resource in which technicians publish and obtain their latest research results on RE, but also an important way of reflecting the updated progress in RE research field. The Journal of Rare Earths covers all research and application of RE rare earths including spectroscopy, luminescence and phosphors, rare earth catalysis, magnetism and magnetic materials, advanced rare earth materials, RE chemistry & hydrometallurgy, RE metallography & pyrometallurgy, RE new materials, RE solid state physics & solid state chemistry, rare earth applications, RE analysis & test, RE geology & ore dressing, etc.
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