{"title":"Radical Copolymerization of p-Aminophenylcyclopropylmethyl Methacrylate with Methyl Methacrylate","authors":"K. G. Guliyev, V. E. Vahabova","doi":"10.1134/S1070427223050038","DOIUrl":null,"url":null,"abstract":"<p><i>p</i>-Aminophenylcyclopropylmethyl methacrylate monomer was prepared, and its free-radical copolymerization with methyl methacrylate was performed. The monomer and copolymer were characterized by IR and NMR spectroscopy. The relative activity constants of the monomer were determined, and the monomer activity and polarity were calculated by the Alfrey–Price method. The copolymerization constant of <i>p</i>-aminophenylcyclopropylmethyl methacrylate exceeds that of methyl methacrylate; therefore, the copolymer is enriched in units of specifically this comonomer. The copolymers based on <i>p-</i>aminophenylcyclopropylmethyl methacrylate exhibit high biological activity toward Gram-positive (<i>Staphylococcus aureus</i>) and Gram-negative (<i>Escherichia coli</i>) bacteria and toward <i>Candida albicans fungi</i>.</p>","PeriodicalId":757,"journal":{"name":"Russian Journal of Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Applied Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070427223050038","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
p-Aminophenylcyclopropylmethyl methacrylate monomer was prepared, and its free-radical copolymerization with methyl methacrylate was performed. The monomer and copolymer were characterized by IR and NMR spectroscopy. The relative activity constants of the monomer were determined, and the monomer activity and polarity were calculated by the Alfrey–Price method. The copolymerization constant of p-aminophenylcyclopropylmethyl methacrylate exceeds that of methyl methacrylate; therefore, the copolymer is enriched in units of specifically this comonomer. The copolymers based on p-aminophenylcyclopropylmethyl methacrylate exhibit high biological activity toward Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria and toward Candida albicans fungi.
期刊介绍：
Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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