A Simple Method for Synthesizing Nitrogen-Doped Carbon Quantum Dots for Fluorescent "Turn off" Mercury (II) Ion Sensing.

Abstract

Here, straightforward and environmentally friendly fluorescent nitrogen doped carbon quantum dots (N-CQDs) with a high blue fluorescence emission at 455 nm are used for ultrasensitive Hg²⁺ ion detection. Folic acid and urea are used as carbon sources in the carbonization process. Two broad absorption bands at around 280 and 370 nm from UV-Vis spectrum and characteristic absorption peaks from infrared spectrum confirms the successful synthesis of the N-CQDs. Energy dispersive X-Ray analysis confirmed the elemental composition of the N-CQDs. Transmission electron microscopy showed the homogeneous globular morphology of the N-CQDs with an average particle size of 65 nm. Zeta potential measurement established the stability and surface charge of N-CQDs. Dynamic light scattering measurement showed the average size of N-CQDs. With the addition of Hg²⁺ ion to N-CQDs, the blue fluorescence emission is quenched. Moreover, the N-CQDs can be applied to real water sample such as pond water, river water, and tap water. The detection limit is approximately calculated to be 12 nM and linear range is 0-30 parts per billion.