Hydrogel membrane composite reduces fouling and retains ammonium efficiently

IF 15 2区 环境科学与生态学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Ralph Rolly Gonzales, Jing Li, Pengfei Zhang, Ping Xu, Zhan Li, Mengyang Hu, Zhaohuan Mai, Kecheng Guan, Hideto Matsuyama
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引用次数: 0

Abstract

The recovery of pure water and valuable substances from wastewater is a major challenge in the context of the circular economy, requiring advanced separation methods. However, actual membrane separation techniques such as forward osmosis are limited by membrane fouling and selectivity. Here, we synthesized composite membranes by crosslinking polyvinyl alcohol hydrogel, using both glutaraldehyde and borax as crosslinking agents, on top of cellulose ester membranes. We tested these composite membranes on model and real wastewater. Results show that the composite membranes retain ammonium effectively, maintain surface electroneutrality, and exhibit remarkable resistance to fouling by organic and biological contaminants. This is explained by the high hydrophilicity of the membrane surface after application of a hydrogel layer.

水凝胶膜复合材料可减少堵塞并有效截留氨
摘要 从废水中回收纯水和有价值的物质是循环经济背景下的一项重大挑战,需要采用先进的分离方法。然而,实际的膜分离技术(如正渗透)受到膜堵塞和选择性的限制。在此,我们使用戊二醛和硼砂作为交联剂,在纤维素酯膜上交联聚乙烯醇水凝胶,合成了复合膜。我们在模型废水和实际废水中测试了这些复合膜。结果表明,复合膜能有效截留铵,保持表面电中性,并对有机污染物和生物污染物的污垢具有显著的抗性。这得益于涂上水凝胶层后膜表面的高亲水性。
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来源期刊
Environmental Chemistry Letters
Environmental Chemistry Letters 环境科学-工程:环境
CiteScore
32.00
自引率
7.00%
发文量
175
审稿时长
2 months
期刊介绍: Environmental Chemistry Letters explores the intersections of geology, chemistry, physics, and biology. Published articles are of paramount importance to the examination of both natural and engineered environments. The journal features original and review articles of exceptional significance, encompassing topics such as the characterization of natural and impacted environments, the behavior, prevention, treatment, and control of mineral, organic, and radioactive pollutants. It also delves into interfacial studies involving diverse media like soil, sediment, water, air, organisms, and food. Additionally, the journal covers green chemistry, environmentally friendly synthetic pathways, alternative fuels, ecotoxicology, risk assessment, environmental processes and modeling, environmental technologies, remediation and control, and environmental analytical chemistry using biomolecular tools and tracers.
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