Comparison of the symmetric hyperbolic thermodynamically compatible framework with Hamiltonian mechanics of binary mixtures

Abstract

How to properly describe continuum thermodynamics of binary mixtures where each constituent has its own momentum? The Symmetric Hyperbolic Thermodynamically Consistent (SHTC) framework and Hamiltonian mechanics in the form of the General Equation for Non-Equilibrium Reversible-Irreversible Coupling (GENERIC) provide two answers, which are similar but not identical, and are compared in this article. They are compared both analytically and numerically on several levels of description, varying in the amount of detail. Namely, a reduction to a more common one-momentum setting is shown, where the effects of the second momentum translate into diffusive fluxes. Both SHTC and GENERIC can thus be interpreted as a method specifying diffusive flux in standard theory. The GENERIC equations, stemming from the Liouville equation, contain terms expressing self-advection of the relative velocity by itself, which lead to a vorticity-dependent diffusion matrix after the reduction. The SHTC equations, on the other hand, do not contain such terms. We also discuss the possibility to formulate a theory of mixtures with two momenta and only one temperature that is compatible with the Liouville equation and possesses the Hamiltonian structure, including Jacobi identity.