Welding Processing of Medium-Manganese Austenitic Steels for Cryogenic Applications

C. Reppin, A. Gericke, K.-M. Henkel, P. Neef, K. Treutler, V. Wesling
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Abstract

For several years, the significance of gaseous energy sources (e. g. liquified natural gas and hydrogen) has been increasing worldwide due to environmental and climate policy requirements. Storage and transportation of the liquids occur under cryogenic conditions. This results in specific requirements for the mechanical properties of the materials used at cryogenic temperatures. Nowadays, cold-tough, high-nickel austenites and martensitic steels of type X8Ni9 are used for such purposes. While austenitic materials offer good processing properties, they are not attractive due to their comparatively low strength and high costs. Welding martensitic steel with commonly used nickel-based additives significantly impacts processing quality and process automation due to high magnetic remanence. Additionally, the increased requirements for the storage of liquid hydrogen regarding low-temperature toughness push the conventional low-temperature materials to their limits. A potential solution to the identified challenges can be achieved by using medium- and high-manganese austenitic steels. Within the scope of this work, the medium-manganese steel X2CrMnNiN1775 (1.4371) is investigated as an economical substitute for the conventionally used materials in cryogenic applications. Considering the relevant qualification requirements for welded joints and welding additives, submerged arc welded joints are investigated and their applicability under cryogenic operating temperatures is demonstrated.
用于低温应用的中锰奥氏体钢的焊接加工
几年来,由于环境和气候政策的要求,气态能源(如液化天然气和氢)在全球范围内的重要性与日俱增。液体的储存和运输都是在低温条件下进行的。这就对在低温条件下使用的材料的机械性能提出了特殊要求。目前,X8Ni9 型冷韧高镍奥氏体钢和马氏体钢已用于此类目的。虽然奥氏体材料具有良好的加工性能,但由于其强度相对较低且成本较高,因此并不具有吸引力。使用常用的镍基添加剂对马氏体钢进行焊接,会因高磁剩磁而严重影响加工质量和加工自动化。此外,液氢储存对低温韧性要求的提高也将传统低温材料推向了极限。中锰奥氏体钢和高锰奥氏体钢是应对上述挑战的潜在解决方案。在本研究范围内,研究了中锰钢 X2CrMnNiN1775 (1.4371),将其作为低温应用中传统材料的经济替代品。考虑到对焊接接头和焊接添加剂的相关资格要求,对埋弧焊接头进行了研究,并证明了其在低温操作温度下的适用性。
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