{"title":"Direct synthesis of porous aluminum nitride foams for enhancing heat transfer and anti-leakage performance of phase change materials","authors":"Rui Chen, Deheng Li, Nan Sheng, Chunyu Zhu","doi":"10.1016/j.tca.2024.179706","DOIUrl":null,"url":null,"abstract":"<div><p>Organic phase change materials (PCMs) suffer from low thermal conductivity and easy leakage, which limit their application in heat storage and thermal management. In this work, porous AlN skeletons were synthesized to solve these problems of paraffin PCM. Using Al powders as raw material, porous AlN skeletons were prepared through the ice-templated method and the direct nitridation reaction. The skeletons were impregnated with paraffin to prepare phase change composites (PCCs). The thermal conductivity of the PCC with 55.6 wt% AlN reaches 9.1 W m<sup>−1</sup> K<sup>−1</sup> in the axial direction, which is 4550 % of paraffin. This PCC retains a high enthalpy of 105 J g<sup>−1</sup> and has good thermal stability. Moreover, the porous AlN skeletons can effectively absorb paraffin so that all PCCs maintain a stable shape. This study provides a simple and efficient method to synthesize porous AlN and to solve the heat conduction and leakage issues of PCMs.</p></div>","PeriodicalId":23058,"journal":{"name":"Thermochimica Acta","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Thermochimica Acta","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040603124000455","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Organic phase change materials (PCMs) suffer from low thermal conductivity and easy leakage, which limit their application in heat storage and thermal management. In this work, porous AlN skeletons were synthesized to solve these problems of paraffin PCM. Using Al powders as raw material, porous AlN skeletons were prepared through the ice-templated method and the direct nitridation reaction. The skeletons were impregnated with paraffin to prepare phase change composites (PCCs). The thermal conductivity of the PCC with 55.6 wt% AlN reaches 9.1 W m−1 K−1 in the axial direction, which is 4550 % of paraffin. This PCC retains a high enthalpy of 105 J g−1 and has good thermal stability. Moreover, the porous AlN skeletons can effectively absorb paraffin so that all PCCs maintain a stable shape. This study provides a simple and efficient method to synthesize porous AlN and to solve the heat conduction and leakage issues of PCMs.
期刊介绍:
Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application.
The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta.
The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas:
- New and improved instrumentation and methods
- Thermal properties and behavior of materials
- Kinetics of thermally stimulated processes