Photoconductivity in self-assembled CuO thin films

IF 3.6 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Akhil M. Anand, Aruna Raj, Jishad A. Salam, R. Adithya Nath, R. Jayakrishnan
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Abstract

Self-assembly is the most promising low-cost and high-throughput methodology for nanofabrication. This paper reports the optimization of a self-assembly process at room temperature for the growth of copper oxide (CuO) based nanostructures over a copper substrate using aqueous potassium hydroxide (KOH) solution as the oxidizing agent. The monoclinic phase of CuO nanostructures grown over the copper substrate was confirmed from the X-ray diffraction (XRD) and micro-Raman analysis. The overall chemical composition of nanostructures was confirmed to be that of CuO from its oxidation state using X-ray photoelectron spectroscopy (XPS). Photodetectors were engineered with the structure Cu/CuO/Ag. The photodetectors exhibited a response to both ultraviolet and visible light illumination. The optimized Cu/CuO/Ag structure exhibits a responsivity of ~ 1.65 µA/W, with an ON:OFF ratio of ~ 69 under a bias voltage of 0.01 V. The temporal dependence of photo-response for the optimized photodetector displayed the persistent nature of photoconduction indicating a delay in charge carrier recombination which could potentially be exploited for photovoltaic applications.

Abstract Image

自组装氧化铜薄膜的光电导性
自组装是最有前途的低成本、高通量纳米制造方法。本文报告了使用氢氧化钾(KOH)水溶液作为氧化剂,在室温下优化自组装工艺,在铜基底上生长基于氧化铜(CuO)的纳米结构。通过 X 射线衍射 (XRD) 和微拉曼分析,确认了在铜基底上生长的 CuO 纳米结构的单斜相。利用 X 射线光电子能谱(XPS)从氧化态确认了纳米结构的整体化学成分为氧化铜。光电探测器的结构为 Cu/CuO/Ag。光电探测器对紫外线和可见光照明均有响应。优化后的 Cu/CuO/Ag 结构在 0.01 V 的偏置电压下的响应率约为 1.65 µA/W,导通与关断比约为 69。
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来源期刊
Materials for Renewable and Sustainable Energy
Materials for Renewable and Sustainable Energy MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
7.90
自引率
2.20%
发文量
8
审稿时长
13 weeks
期刊介绍: Energy is the single most valuable resource for human activity and the basis for all human progress. Materials play a key role in enabling technologies that can offer promising solutions to achieve renewable and sustainable energy pathways for the future. Materials for Renewable and Sustainable Energy has been established to be the world''s foremost interdisciplinary forum for publication of research on all aspects of the study of materials for the deployment of renewable and sustainable energy technologies. The journal covers experimental and theoretical aspects of materials and prototype devices for sustainable energy conversion, storage, and saving, together with materials needed for renewable fuel production. It publishes reviews, original research articles, rapid communications, and perspectives. All manuscripts are peer-reviewed for scientific quality. Topics include: 1. MATERIALS for renewable energy storage and conversion: Batteries, Supercapacitors, Fuel cells, Hydrogen storage, and Photovoltaics and solar cells. 2. MATERIALS for renewable and sustainable fuel production: Hydrogen production and fuel generation from renewables (catalysis), Solar-driven reactions to hydrogen and fuels from renewables (photocatalysis), Biofuels, and Carbon dioxide sequestration and conversion. 3. MATERIALS for energy saving: Thermoelectrics, Novel illumination sources for efficient lighting, and Energy saving in buildings. 4. MATERIALS modeling and theoretical aspects. 5. Advanced characterization techniques of MATERIALS Materials for Renewable and Sustainable Energy is committed to upholding the integrity of the scientific record. As a member of the Committee on Publication Ethics (COPE) the journal will follow the COPE guidelines on how to deal with potential acts of misconduct. Authors should refrain from misrepresenting research results which could damage the trust in the journal and ultimately the entire scientific endeavor. Maintaining integrity of the research and its presentation can be achieved by following the rules of good scientific practice as detailed here: https://www.springer.com/us/editorial-policies
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