Akhil M. Anand, Aruna Raj, Jishad A. Salam, R. Adithya Nath, R. Jayakrishnan
{"title":"Photoconductivity in self-assembled CuO thin films","authors":"Akhil M. Anand, Aruna Raj, Jishad A. Salam, R. Adithya Nath, R. Jayakrishnan","doi":"10.1007/s40243-023-00250-7","DOIUrl":null,"url":null,"abstract":"<div><p>Self-assembly is the most promising low-cost and high-throughput methodology for nanofabrication. This paper reports the optimization of a self-assembly process at room temperature for the growth of copper oxide (CuO) based nanostructures over a copper substrate using aqueous potassium hydroxide (KOH) solution as the oxidizing agent. The monoclinic phase of CuO nanostructures grown over the copper substrate was confirmed from the X-ray diffraction (XRD) and micro-Raman analysis. The overall chemical composition of nanostructures was confirmed to be that of CuO from its oxidation state using X-ray photoelectron spectroscopy (XPS). Photodetectors were engineered with the structure Cu/CuO/Ag. The photodetectors exhibited a response to both ultraviolet and visible light illumination. The optimized Cu/CuO/Ag structure exhibits a responsivity of ~ 1.65 µA/W, with an ON:OFF ratio of ~ 69 under a bias voltage of 0.01 V. The temporal dependence of photo-response for the optimized photodetector displayed the persistent nature of photoconduction indicating a delay in charge carrier recombination which could potentially be exploited for photovoltaic applications.</p></div>","PeriodicalId":692,"journal":{"name":"Materials for Renewable and Sustainable Energy","volume":"13 1","pages":"45 - 58"},"PeriodicalIF":3.6000,"publicationDate":"2024-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40243-023-00250-7.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials for Renewable and Sustainable Energy","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.1007/s40243-023-00250-7","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Self-assembly is the most promising low-cost and high-throughput methodology for nanofabrication. This paper reports the optimization of a self-assembly process at room temperature for the growth of copper oxide (CuO) based nanostructures over a copper substrate using aqueous potassium hydroxide (KOH) solution as the oxidizing agent. The monoclinic phase of CuO nanostructures grown over the copper substrate was confirmed from the X-ray diffraction (XRD) and micro-Raman analysis. The overall chemical composition of nanostructures was confirmed to be that of CuO from its oxidation state using X-ray photoelectron spectroscopy (XPS). Photodetectors were engineered with the structure Cu/CuO/Ag. The photodetectors exhibited a response to both ultraviolet and visible light illumination. The optimized Cu/CuO/Ag structure exhibits a responsivity of ~ 1.65 µA/W, with an ON:OFF ratio of ~ 69 under a bias voltage of 0.01 V. The temporal dependence of photo-response for the optimized photodetector displayed the persistent nature of photoconduction indicating a delay in charge carrier recombination which could potentially be exploited for photovoltaic applications.
期刊介绍:
Energy is the single most valuable resource for human activity and the basis for all human progress. Materials play a key role in enabling technologies that can offer promising solutions to achieve renewable and sustainable energy pathways for the future.
Materials for Renewable and Sustainable Energy has been established to be the world''s foremost interdisciplinary forum for publication of research on all aspects of the study of materials for the deployment of renewable and sustainable energy technologies. The journal covers experimental and theoretical aspects of materials and prototype devices for sustainable energy conversion, storage, and saving, together with materials needed for renewable fuel production. It publishes reviews, original research articles, rapid communications, and perspectives. All manuscripts are peer-reviewed for scientific quality.
Topics include:
1. MATERIALS for renewable energy storage and conversion: Batteries, Supercapacitors, Fuel cells, Hydrogen storage, and Photovoltaics and solar cells.
2. MATERIALS for renewable and sustainable fuel production: Hydrogen production and fuel generation from renewables (catalysis), Solar-driven reactions to hydrogen and fuels from renewables (photocatalysis), Biofuels, and Carbon dioxide sequestration and conversion.
3. MATERIALS for energy saving: Thermoelectrics, Novel illumination sources for efficient lighting, and Energy saving in buildings.
4. MATERIALS modeling and theoretical aspects.
5. Advanced characterization techniques of MATERIALS
Materials for Renewable and Sustainable Energy is committed to upholding the integrity of the scientific record. As a member of the Committee on Publication Ethics (COPE) the journal will follow the COPE guidelines on how to deal with potential acts of misconduct. Authors should refrain from misrepresenting research results which could damage the trust in the journal and ultimately the entire scientific endeavor. Maintaining integrity of the research and its presentation can be achieved by following the rules of good scientific practice as detailed here: https://www.springer.com/us/editorial-policies