Julien Lemieux , Imran Aslam , Vincent Lemmens , Guy Van den Mooter , Gordana Backović , Samuel Eyley , Wim Thielemans
{"title":"Insect-powered electrochemical capacitors: The potential of cricket biomass","authors":"Julien Lemieux , Imran Aslam , Vincent Lemmens , Guy Van den Mooter , Gordana Backović , Samuel Eyley , Wim Thielemans","doi":"10.1016/j.cartre.2024.100329","DOIUrl":null,"url":null,"abstract":"<div><p>Insect biomass, rich in chitin and chitosan, is a sustainable and abundant resource with substantial promise for advancing green energy storage solutions. In this study, we explored cricket flour as a biomass candidate for carbon electrodes in electrochemical capacitors, aiming at creating a material with a high nitrogen content upon carbonization. The optimized material boasted a specific surface area exceeding 3300 m<sup>2</sup>/g, with most pores falling within the 0.5–2 nm diameter range. In a symmetrical Swagelok-type cell, this material delivered exceptional performance, yielding capacitances of 273.5 F/g, 200.2 F/g, and 161.6 F/g at 1 A/g in 6 M KOH, 1 M H<sub>2</sub>SO<sub>4</sub>, and 9.2 M NaClO<sub>4</sub> electrolytes, respectively. Furthermore, it showcased a capacity retention of 89.6 % and 87.9 % over 5000 cycles in 1 M H<sub>2</sub>SO<sub>4</sub> and 6 M KOH, respectively. The cricket-based electrochemical capacitor exhibited robust cycling stability, suggesting its suitability for prolonged use. The resulting device demonstrated remarkably high specific capacitance, positioning it as a promising candidate for energy storage applications.</p></div>","PeriodicalId":52629,"journal":{"name":"Carbon Trends","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667056924000105/pdfft?md5=3c5ff6ccf3e479bbf41f1e4c05373503&pid=1-s2.0-S2667056924000105-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Trends","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667056924000105","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Insect biomass, rich in chitin and chitosan, is a sustainable and abundant resource with substantial promise for advancing green energy storage solutions. In this study, we explored cricket flour as a biomass candidate for carbon electrodes in electrochemical capacitors, aiming at creating a material with a high nitrogen content upon carbonization. The optimized material boasted a specific surface area exceeding 3300 m2/g, with most pores falling within the 0.5–2 nm diameter range. In a symmetrical Swagelok-type cell, this material delivered exceptional performance, yielding capacitances of 273.5 F/g, 200.2 F/g, and 161.6 F/g at 1 A/g in 6 M KOH, 1 M H2SO4, and 9.2 M NaClO4 electrolytes, respectively. Furthermore, it showcased a capacity retention of 89.6 % and 87.9 % over 5000 cycles in 1 M H2SO4 and 6 M KOH, respectively. The cricket-based electrochemical capacitor exhibited robust cycling stability, suggesting its suitability for prolonged use. The resulting device demonstrated remarkably high specific capacitance, positioning it as a promising candidate for energy storage applications.