Recent progress of MXene as a cocatalyst in photocatalytic carbon dioxide reduction

Abstract

Due to the excessive consumption of fossil fuel resources and the emission of a substantial quantity of CO₂ into the environment, it is urgent to develop clean energy solutions. In order to reduce carbon emissions from the source, it is effective approach to convert CO₂ into various renewable energy fuels. Inspired by the photosynthesis of green plant, CO₂ is converted into clean fuel with the aid of catalysts. Regarding the separation and transfer of photogenerated charge carriers, and inadequate adsorption and activation of CO₂ on the surface of catalysts, the current semiconductors utilized in photocatalysis have low efficiency. As a result, the current efficiency of photocatalysts is far from meeting the need for practical industrial demands. MXene materials, for example Ti₃C₂T_x (9980 S cm⁻¹), have emerged as a promising candidate for CO₂ reduction due to the significant number of active sites for functional groups, high conductivity and low defects, large surface areas, and outstanding visible light photoelectronic properties. This review provides a critical overview of the recent progress regarding MXene as a co-catalyst in photocatalytic CO₂ reduction systems. We systemically explore the fundamental principles and reaction mechanisms associated with separating and transferring photogenerated charge carriers. Additionally, we investigate the basic properties of MXene as a co-catalyst in the context of CO₂ reduction. Furthermore, this review also elucidates the impacts of the microstructure of photocatalysts on enhancing photocatalytic performance. Finally, the challenges and opportunities in using MXene as a co-catalyst for CO₂ reduction have been presented to inspire further research in this field.