BASIC METHODS OF MONITORING OF CORROSION PROCESSES OF CEMENT STRUCTURES AND THEIR IMPLEMENTATION FOR PROJECTING OF POSSIBLE MINERALOGICAL CHANGES IN MATRIX COMPOSITION: REVIEW

Yu. O. Kovalenko
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Abstract

Long time service of concrete constructions is accompanied by continuous impact of environment on its structural integrity and capability to carry project capacity of constructions. This influences are able to change not only chemical composition of cement matrix but itself activates corrosion processes that have place to occur on the joints of metal rebar and cement matrix in reinforced concrete (RC). Chemical initiation in the reinforced concrete begins due to the migration of water with parts of molecular oxygen in the thickness of concrete via porous structure of material. The same can be said about the injected compounds of either SO4 2- or Clcomponents that both can be present either in environment or concrete itself due to the modifications of slurry. Such occurrences usually accompanied by changes of pH of the environment that is crucial for the electrolytic environment to appear. Therefore, the process of the reduction of water/ proton may begin at rebar surface wich is the cause not only of the reinforced concrete rebar corrosion but also are reason of accelerated cement matrix degradation. Also, must be noted, that steel corrosion in RC accompanied by changes in current flow. Thus, by understanding the chemical processes and changes that occur in cement matrix of concrete and basics of steel corrosion initiation under the influence of aggressive solutions, the list of non-destructive methods of monitoring (NDM) based on electrical methods of monitoring are reviewed. Different approaches using electrical methods of corrosion monitoring has shown that the use of any of the technics either measurements of the corrosion potential or concrete resistivity or polarization resistance provides different results in mapping of areas with high corrosion risks, monitoring of the heterogeneity of concrete and insights on transport phenomena (e.g. water and salts ingress) in the material. Moreover, advances in potential monitoring without connection to the rebar as non-destructive measurements have shown their effectiveness. Nevertheless, colligation of the results of both numerical and NDM methods is necessary for assortment the results to provide a better data of the worktime of RC structures.
监测水泥结构腐蚀过程的基本方法及其在预测基体成分可能发生的矿物学变化方面的应用:综述
随着混凝土建筑的长期使用,环境对其结构完整性和承载建筑工程能力的持续影响也随之而来。这种影响不仅会改变水泥基质的化学成分,而且会激活钢筋混凝土(RC)中金属钢筋和水泥基质连接处的腐蚀过程。钢筋混凝土中的化学反应开始于含部分分子氧的水通过材料的多孔结构迁移到混凝土的厚度。注入的 SO4 2- 或 Cl 成分的化合物也是如此,由于泥浆的改性,这两种化合物都可能存在于环境或混凝土本身中。这种情况通常伴随着环境 pH 值的变化,而 pH 值的变化对于电解环境的出现至关重要。因此,水/质子的还原过程可能从钢筋表面开始,这不仅是钢筋混凝土钢筋腐蚀的原因,也是水泥基质加速降解的原因。此外,必须注意的是,钢筋混凝土中的钢筋腐蚀伴随着电流的变化。因此,通过了解混凝土水泥基质中发生的化学过程和变化,以及在侵蚀性溶液影响下引发钢筋腐蚀的基本原理,我们对基于电气监测方法的无损监测(NDM)方法清单进行了回顾。使用电学方法进行腐蚀监测的不同方法表明,使用任何一种技术,无论是测量腐蚀电位还是混凝土电阻率或极化电阻,都能在绘制高腐蚀风险区域图、监测混凝土的异质性以及深入了解材料中的迁移现象(如水和盐的进入)方面提供不同的结果。此外,不与钢筋连接的非破坏性测量在电位监测方面的进步也显示了其有效性。不过,有必要将数值方法和非破坏性测量方法的结果综合起来,以便为 RC 结构的工作时间提供更好的数据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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