Early strength enhancement of high-volume fly ash mortar using accelerating admixtures

Hung Vu Viet, Quang Le Van
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Abstract

High-volume fly ash mortar is considered a "green" material, a sustainable development solution for the construction industry, in which the fly ash replacement Portland cement content is over 50%. However, this material has the major disadvantage of slow strength development, especially at an early age, which limits its applicability. To overcome the above disadvantage, the individual or combined addition of lime Ca(OH)2, silica fume, and/or accelerating admixtures including sodium thiocyanate (NaSCN), diethanolamine (DEA), and glycerol (Gly), etc. have been interested recently. In this study, to enhance the early strength of mortars with fly ash content to replace 60÷80% of Portland cement, a three-component accelerating admixture of NaSCN, DEA, and Gly (2:1:0.5 by the mass) was used with different ratios of 0.21÷0.49 % by the total powder mass, combined with a reasonable amount of lime, silica fume supplement as presented in previous research. Experimental results showed that the optimal accelerating admixture content is 0.35% by weight of powder, combined with 6% silica fume and the additional amount of lime is 5%; 10%; and 15% corresponding to mortars using fly ash of 60%; 70% and 80%, respectively to improve early strength of mortars that are suitable for structural use (R3 ≥ 13MPa, 3 days old). In addition, the influence of the additives used on the initial setting time of high-volume fly ash mortars was also discussed.
使用加速外加剂提高大体积粉煤灰砂浆的早期强度
高体积粉煤灰砂浆被认为是一种 "绿色 "材料,是建筑业可持续发展的解决方案,其中粉煤灰替代硅酸盐水泥的含量超过 50%。然而,这种材料的主要缺点是强度发展缓慢,尤其是在早期龄期,这限制了它的适用性。为了克服上述缺点,近年来,单独或联合添加石灰 Ca(OH)2、硅灰和/或加速外加剂(包括硫氰酸钠 (NaSCN)、二乙醇胺 (DEA) 和甘油 (Gly) 等)引起了人们的兴趣。在这项研究中,为了提高粉煤灰含量取代 60% 至 80% 硅酸盐水泥的砂浆的早期强度,使用了 NaSCN、DEA 和 Gly(2:1:0.5 质量比)的三组份加速外加剂,其不同的比例为总粉料质量的 0.21% 至 0.49%,并结合前人研究中提出的适量石灰、硅灰补充剂。实验结果表明,最佳的加速掺合料含量为粉料重量的 0.35%,结合 6%的硅灰和 5%、10%和 15%的石灰添加量,分别对应于粉煤灰用量为 60%、70%和 80%的砂浆,以提高适合结构使用的砂浆的早期强度(R3 ≥ 13MPa,3 天龄期)。此外,还讨论了所用添加剂对大体积粉煤灰砂浆初凝时间的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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