Variable heterotridentate ligands in Pt(ƞ3-X1C1X2)(PL) (X1,2 = N or S), Pt(ƞ3-X1N1Y1)(PL) (X, Y = O, C; C, S; or O, S) and Pt(ƞ3-S1B1S2)(PL), derivatives – structural aspects

IF 4.1 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Reviews in Inorganic Chemistry Pub Date : 2024-01-19 DOI:10.1515/revic-2023-0029

Milan Melník, Dominika Žigrayová, Veronika Mikušová, Peter Mikuš

引用次数: 0

Abstract

This review covers 17 Pt(II) complexes of the compositions: Pt(ƞ3-N1C1N2)(PL), Pt(ƞ3-S1C1S2)(PL), Pt(ƞ3-S1B1S2)(PL), Pt(ƞ3-S1S2O1)(PL), Pt(ƞ3-O1N1C1)(PL), Pt(ƞ3-O1N1S1)(PL) and Pt(ƞ3-C1N1S1)(PL). These complexes crystallized in three crystal classes: monoclinic (8 examples), triclinic (8 examples) and orthorhombic (1 example). The heterotridentate ligands creates 5 + 5-membered metallocyclic rings (most common) and 5 + 6-membered. The heterotridentate ligands with monodentate P ligands build up a distorted square-planar geometry about Pt(II) atoms. The Pt–L and L–Pt–L were analyzed. The τ 4 parameter which indicate a degree of distortion growing in the sentence: 0.057 Pt(ƞ3-O1N1S1)(PL) < 0.066 Pt(ƞ3-S1C1S2)(PL) < 0.149 Pt(ƞ3-S1S2O1)(PL) < 0.158 Pt(ƞ3-O1N1C1)(PL) < 0.160 Pt(ƞ3-C1N1S1)(PL) < 0.162 Pt(ƞ3-S1B1S2)(PL) < 0.165 Pt(ƞ3-N1C1N2)(PL).

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铂(ƞ3-X1C1X2)(PL)（X1,2 = N 或 S）、铂(ƞ3-X1N1Y1)(PL)（X, Y = O, C; C, S; 或 O, S）和铂(ƞ3-S1B1S2)(PL)中的可变异戟配体，衍生物 - 结构方面的问题

本综述涉及 17 种铂(II)络合物的组成：Pt(ƞ3-N1C1N2)(PL)、Pt(ƞ3-S1C1S2)(PL)、Pt(ƞ3-S1B1S2)(PL)、Pt(ƞ3-S1S2O1)(PL)、Pt(ƞ3-O1N1C1)(PL)、Pt(ƞ3-O1N1S1)(PL) 和 Pt(ƞ3-C1N1S1)(PL)。这些配合物以三种晶体类别结晶：单斜（8 例）、三斜（8 例）和正交（1 例）。杂三齿配体形成了 5 + 5 元金属环（最常见）和 5 + 6 元金属环。带有单齿 P 配体的杂三叉配体会围绕铂（II）原子形成扭曲的方形平面几何。分析了 Pt-L 和 L-Pt-L。表示畸变程度的 τ 4 参数在句子中不断增加：0.057 Pt(ƞ3-O1N1S1)(PL) < 0.066 Pt(ƞ3-S1C1S2)(PL) < 0.149 Pt(ƞ3-S1S2O1)(PL) < 0.158 Pt(ƞ3-O1N1C1)(PL) < 0.160 Pt(ƞ3-C1N1S1)(PL) < 0.162 Pt(ƞ3-S1B1S2)(PL) < 0.165 Pt(ƞ3-N1C1N2)(PL).

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Reviews in Inorganic Chemistry 化学-分析化学

CiteScore

7.30

自引率

4.90%

发文量

审稿时长

1 months

期刊介绍： Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids