Jin Young Oh , Bo-Kyeong Choi , Dong Wook Lee , Liu Yang , Dae-Shik Seo
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引用次数: 0
Abstract
The brush coating method allows the advantage of being able to produce thin films simply and quickly. This study introduces a method for thin-film production by brushing a solution containing graphene doped in Al2O3 using the sol–gel method. Graphene oxide (GO) is suitable for semiconductors with bandgap values of about 1.7 eV at room temperature, and the characteristics of the thin films were analyzed according to the doping ratio. First, X-ray photoelectron spectroscopy measurements were obtained to analyze the chemical composition of the thin-film surface. Since graphene is a carbon isomer, the characteristic of oxygen vacancies was confirmed by the increasing C–C bond intensity with increasing GO doping concentration. In addition, Raman analysis was performed to analyze the concentration of molecular groups of compounds for defects in graphene. Thereafter, through atomic force microscopy measurements, as the graphene doping ratio increased, the average roughness increased from 1.785 to 33.67, the residual DC voltage also increased by about 48.42 %, and the polar anchoring energy also increased by about 16.33 %. In addition, response-time–transmittance measurements were performed to measure the electro-optical properties of the thin film, and excellent Vth and stable response speed were obtained. Additionally, the validity of the results was supported through bandgap analysis. Finally, the degree of alignment of liquid–crystal molecules on the film surface was confirmed by polarized optical microscopy and pretilt angle measurements, and the suitability of the thin film for display devices was shown via transmittance measurements. As a result, GO:Al2O3 hybrid thin film is an excellent candidate for use as an alignment film for solar energy, secondary batteries, and next-generation liquid crystal displays.
期刊介绍:
FlatChem - Chemistry of Flat Materials, a new voice in the community, publishes original and significant, cutting-edge research related to the chemistry of graphene and related 2D & layered materials. The overall aim of the journal is to combine the chemistry and applications of these materials, where the submission of communications, full papers, and concepts should contain chemistry in a materials context, which can be both experimental and/or theoretical. In addition to original research articles, FlatChem also offers reviews, minireviews, highlights and perspectives on the future of this research area with the scientific leaders in fields related to Flat Materials. Topics of interest include, but are not limited to, the following: -Design, synthesis, applications and investigation of graphene, graphene related materials and other 2D & layered materials (for example Silicene, Germanene, Phosphorene, MXenes, Boron nitride, Transition metal dichalcogenides) -Characterization of these materials using all forms of spectroscopy and microscopy techniques -Chemical modification or functionalization and dispersion of these materials, as well as interactions with other materials -Exploring the surface chemistry of these materials for applications in: Sensors or detectors in electrochemical/Lab on a Chip devices, Composite materials, Membranes, Environment technology, Catalysis for energy storage and conversion (for example fuel cells, supercapacitors, batteries, hydrogen storage), Biomedical technology (drug delivery, biosensing, bioimaging)