Enhanced photocatalytic degradation of organic pollutants in water using copper oxide (CuO) nanosheets for environmental application

Abstract

Rapid, inexpensive, and low-power/solar light-driven photocatalytic degradation of organic pollutants to deal with annually produced trillion tons of synthetic dye wastewater to prevent water scarcity issues, ecotoxicological risks, and human health has always been challenging. To overcome this limitation, the present study synthesized earth-abundant, inexpensive copper oxide nanosheets using a simple single-step hydrothermal route. The structural, physicochemical, and functional properties of the nanosheets have been characterized using several characterization techniques. The photocatalytic activity was studied for two commonly industrially used organic dyes, Methylene Blue (MB) and Rhodamine B (RhB). The importance of this work is the usage of a cheap commercially available Phillips UV light (11 W) as well as direct sunlight. With several optimized conditions, almost complete degradation of both dyes was achieved within 35 minutes under low-power UV light and within 70 minutes by the direct illumination of natural sunlight. The enhanced photocatalytic performance can be correlated to the synergetic effect of a higher charge transfer mechanism, good catalytic ‘active surface area’ availability (13.2 m²/g), and several optimized parameters that affect the reaction efficacy. Additionally, five repeated uses of nanosheets without sacrificing performance confirmed their stability and sustainability as a promising candidate for large-scale industrial textile wastewater remedies.