Synthesis, characterization, degradation and applications of vinyl polyperoxides

IF 2.3 4区化学 Q3 POLYMER SCIENCE

Polymer Journal Pub Date : 2024-01-10 DOI:10.1038/s41428-023-00860-y

Pousali Samanta, Sourav Mete, Sunirmal Pal, Md Ezaz Hasan Khan, Priyadarsi De

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Abstract

Polymeric peroxide is an equimolar alternating copolymer formed by the reaction of a monomer with molecular oxygen (O2). Various polyperoxides have been successfully synthesized using different techniques, such as free radical polymerization, condensation polymerization, and insertion polymerization in the solid state. A wide variety of physical and chemical characteristics are displayed by these polyperoxides, making them attractive candidates for various applications. Due to their high exothermal degrading behavior and autocombustibility, polyperoxides are a viable alternative to fuels derived from petroleum. Additionally, polyperoxides have a wide range of applications, such as free radical initiators, curatives, biocompatible drug carriers, coating materials, dismantlable adhesives, and molding precursors. In this focused review, we report on recent efforts in developing vinyl homo- and copolyperoxides, their physicochemical behaviors, and various applications. Finally, the existing opportunities, possible challenges, and some viewpoints on future directions in vinyl polyperoxide research are highlighted. Our recent studies on the synthesis, characterization, degradation and applications of vinyl polyperoxides are reviewed. Primarily, the recent achievements in the design, biocompatibility, thermal and enzymatic degradation of water-soluble vinyl polyperoxides and copolyperoxides are described. Finally, future development possibilities and challenges of vinyl polyperoxides for various potential applications are summarised.

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乙烯基聚过氧化物的合成、表征、降解和应用

聚合过氧化物是单体与分子氧（O2）反应形成的等摩尔交替共聚物。目前已利用自由基聚合、缩合聚合和固态插入聚合等不同技术成功合成了各种聚过氧化物。这些聚过氧化物具有多种物理和化学特性，因此在各种应用中都很有吸引力。由于具有较高的放热降解性能和自燃性，聚过氧化物是石油燃料的可行替代品。此外，聚过氧化物还具有广泛的用途，如自由基引发剂、固化剂、生物相容性药物载体、涂层材料、可拆卸粘合剂和成型前体。在这篇重点综述中，我们报告了最近在开发乙烯基均过氧化物和共过氧化物方面所做的努力、它们的物理化学行为以及各种应用。最后，我们将重点介绍乙烯基过氧化物研究的现有机遇、可能面临的挑战以及对未来发展方向的一些看法。

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来源期刊

Polymer Journal 化学-高分子科学

CiteScore

5.60

自引率

7.10%

发文量

131

审稿时长

2.5 months

期刊介绍： Polymer Journal promotes research from all aspects of polymer science from anywhere in the world and aims to provide an integrated platform for scientific communication that assists the advancement of polymer science and related fields. The journal publishes Original Articles, Notes, Short Communications and Reviews. Subject areas and topics of particular interest within the journal''s scope include, but are not limited to, those listed below: Polymer synthesis and reactions Polymer structures Physical properties of polymers Polymer surface and interfaces Functional polymers Supramolecular polymers Self-assembled materials Biopolymers and bio-related polymer materials Polymer engineering.