PREPARATION AND CHARACTERIZATION OF FLY ASH ADDITIVE MODIFIED POLIESTER BASED MEMBRANE

Januar Efendi, Sri - Aprilia, F. Djuned
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Abstract

Recently, Polyethersulfone (PES) polymer material based on flat sheet membranes reached much attention in membrane technology. However, PES polymer has low hydrophilicity. This study describes PES-based membranes incorporating fly ash as an additive. The first analysis was conducted by Fourier Transform Infrared, Scanning Electron Microscope, tensile strength, and porosity tests. Four membranes, including pure PES membranes, were prepared via the phase inversion process, namely MA–0, MA–0.1, MA–1, and MS–1. The characteristics of the membrane samples were analyzed in terms of chemical group, morphology, mechanical and membrane surface hydrophilicity. The characterization results show that additive incorporation increased pure water flux performance, and the highest pure water permeability increased up to 70% by the MA–1 membrane. Moreover, it increased by 19% compared to pure silica-modified PES membrane (MS–1). In addition, the MA-1 membrane at a pressure of 3 bar reached significant performance in the trend of pure water flux values because of these improvements in membrane characteristics. The membrane also shows a higher tensile strength with adding additives to the membrane prepared.
粉煤灰添加剂改性聚酯基膜的制备与表征
最近,基于聚醚砜(PES)聚合物材料的平板膜在膜技术领域备受关注。然而,PES 聚合物的亲水性较低。本研究介绍了以粉煤灰为添加剂的 PES 膜。首先通过傅立叶变换红外线、扫描电子显微镜、拉伸强度和孔隙率测试进行了分析。通过相反转工艺制备了四种膜,包括纯 PES 膜,即 MA-0、MA-0.1、MA-1 和 MS-1。从化学组、形态、机械和膜表面亲水性等方面分析了膜样品的特性。表征结果表明,添加剂的加入提高了纯水通量性能,MA-1 膜的纯水渗透率最高提高了 70%。而且,与纯硅改性 PES 膜(MS-1)相比,纯水渗透率提高了 19%。此外,由于膜特性的改善,MA-1 膜在 3 巴压力下的纯水通量值趋势表现显著。在制备的膜中添加添加剂后,膜还显示出更高的拉伸强度。
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