On the performance of vertical MoS2 nanoflakes as a photoelectrochemical studies for energy application

Q1 Materials Science
K. Kaviyarasu , J. Madhavan
{"title":"On the performance of vertical MoS2 nanoflakes as a photoelectrochemical studies for energy application","authors":"K. Kaviyarasu ,&nbsp;J. Madhavan","doi":"10.1016/j.mset.2023.12.003","DOIUrl":null,"url":null,"abstract":"<div><p>With the help of a hydrothermal process, we were able to prepare vertically layered MoS<sub>2</sub> nanoflakes that were rooted to TiO<sub>2</sub> modified. MoS<sub>2</sub> nanoflakes and TiO<sub>2</sub> contribute significantly to the strong XRD peaks and μ-Raman spectroscopy, and this phenomenon may also be explained by the unique structure of vertically stacked MoS<sub>2</sub> nanoflakes on TiO<sub>2</sub> that has many exposed edges and large surfaces as well as high electron transfer rates between TiO<sub>2</sub> and MoS<sub>2</sub>. As can be clearly seen, there are no noticeable changes in the self-photodegradation of MB under visible light interaction (VLI), and the MoS<sub>2</sub> doped TiO<sub>2</sub> photocatalyst displays ∼ 90 % degradation efficiency. By, measuring photoelectrochemically, charge carriers are separated efficiently. These experiments illustrate the transient photocurrent response of the MoS<sub>2</sub> doped TiO<sub>2</sub> photocatalyst while cycling between three on/off cycles. As a result of a low recombination rate of the photoexcited charge carriers, the MoS<sub>2</sub> doped TiO<sub>2</sub> photocatalyst displays superior photocurrent response. In other words, a lower charge transfer resistance results in a faster transfer of charge between the surfaces.</p></div>","PeriodicalId":18283,"journal":{"name":"Materials Science for Energy Technologies","volume":"7 ","pages":"Pages 249-256"},"PeriodicalIF":0.0000,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2589299123000691/pdfft?md5=763847204f160863148bf2d61ea5b0b9&pid=1-s2.0-S2589299123000691-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science for Energy Technologies","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589299123000691","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 0

Abstract

With the help of a hydrothermal process, we were able to prepare vertically layered MoS2 nanoflakes that were rooted to TiO2 modified. MoS2 nanoflakes and TiO2 contribute significantly to the strong XRD peaks and μ-Raman spectroscopy, and this phenomenon may also be explained by the unique structure of vertically stacked MoS2 nanoflakes on TiO2 that has many exposed edges and large surfaces as well as high electron transfer rates between TiO2 and MoS2. As can be clearly seen, there are no noticeable changes in the self-photodegradation of MB under visible light interaction (VLI), and the MoS2 doped TiO2 photocatalyst displays ∼ 90 % degradation efficiency. By, measuring photoelectrochemically, charge carriers are separated efficiently. These experiments illustrate the transient photocurrent response of the MoS2 doped TiO2 photocatalyst while cycling between three on/off cycles. As a result of a low recombination rate of the photoexcited charge carriers, the MoS2 doped TiO2 photocatalyst displays superior photocurrent response. In other words, a lower charge transfer resistance results in a faster transfer of charge between the surfaces.

Abstract Image

关于垂直 MoS2 纳米片在能源应用中的光电化学性能研究
在水热法的帮助下,我们制备出了垂直分层的 MoS2 纳米片,并将其根植于改性的 TiO2 上。MoS2纳米片和TiO2对强XRD峰和μ-拉曼光谱有很大的贡献,这一现象也可能是由于垂直堆积的MoS2纳米片在TiO2上具有独特的结构,即有许多暴露的边缘和大的表面,以及TiO2和MoS2之间的高电子转移率。可以清楚地看到,在可见光相互作用(VLI)下,甲基溴的自光降解没有发生明显变化,掺杂 MoS2 的 TiO2 光催化剂的降解效率高达 90%。通过光电化学测量,电荷载流子被有效分离。这些实验说明了掺杂 MoS2 的二氧化钛光催化剂在三个开/关循环之间的瞬态光电流响应。由于光激发电荷载流子的重组率较低,掺杂 MoS2 的二氧化钛光催化剂显示出卓越的光电流响应。换句话说,较低的电荷转移电阻可加快表面之间的电荷转移。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Materials Science for Energy Technologies
Materials Science for Energy Technologies Materials Science-Materials Science (miscellaneous)
CiteScore
16.50
自引率
0.00%
发文量
41
审稿时长
39 days
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信