On the Ytterbium Valence and the Physical Properties in Selected Intermetallic Phases

IF 3.3 Q2 CHEMISTRY, MULTIDISCIPLINARY
Stefan Engel, Elias C. J. Gießelmann, Maximilian K. Reimann, Rainer Pöttgen* and Oliver Janka*, 
{"title":"On the Ytterbium Valence and the Physical Properties in Selected Intermetallic Phases","authors":"Stefan Engel,&nbsp;Elias C. J. Gießelmann,&nbsp;Maximilian K. Reimann,&nbsp;Rainer Pöttgen* and Oliver Janka*,&nbsp;","doi":"10.1021/acsorginorgau.3c00054","DOIUrl":null,"url":null,"abstract":"<p >The present review summarizes important aspects of the crystal chemistry of ytterbium-based intermetallic compounds along with a selection of their outstanding physical properties. These originate in many cases from the ytterbium valence. Different valence states are possible here, divalent (4f<sup>14</sup>), intermediate-valent, or trivalent (4f<sup>13</sup>) ytterbium, resulting in simple diamagnetic, Pauli or Curie–Weiss paramagnetic, or valence fluctuating behavior. Especially, some of the Yb<sup>3+</sup> intermetallics have gained deep interest due to their Kondo or heavy Fermion ground states. We have summarized their property investigations using magnetic and transport measurements, specific heat data, NMR, ESR, and Mössbauer spectroscopy, elastic and inelastic neutron scattering, and XAS data as well as detailed thermoelectric measurements.</p>","PeriodicalId":29797,"journal":{"name":"ACS Organic & Inorganic Au","volume":"4 2","pages":"188–222"},"PeriodicalIF":3.3000,"publicationDate":"2024-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsorginorgau.3c00054","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Organic & Inorganic Au","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsorginorgau.3c00054","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

The present review summarizes important aspects of the crystal chemistry of ytterbium-based intermetallic compounds along with a selection of their outstanding physical properties. These originate in many cases from the ytterbium valence. Different valence states are possible here, divalent (4f14), intermediate-valent, or trivalent (4f13) ytterbium, resulting in simple diamagnetic, Pauli or Curie–Weiss paramagnetic, or valence fluctuating behavior. Especially, some of the Yb3+ intermetallics have gained deep interest due to their Kondo or heavy Fermion ground states. We have summarized their property investigations using magnetic and transport measurements, specific heat data, NMR, ESR, and Mössbauer spectroscopy, elastic and inelastic neutron scattering, and XAS data as well as detailed thermoelectric measurements.

Abstract Image

Abstract Image

某些金属间化合物中的镱价和物理性质
本综述总结了镱基金属间化合物晶体化学的一些重要方面,以及它们的一些突出物理性质。在许多情况下,这些特性源于镱的价态。二价(4f14)、中价或三价(4f13)镱的不同价态可能导致简单的二磁性、保利或居里-魏斯顺磁性或价态波动行为。特别是一些 Yb3+ 金属间化合物因其近藤基态或重费米子基态而引起了人们的浓厚兴趣。我们利用磁性和传输测量、比热数据、核磁共振、ESR 和莫斯鲍尔光谱、弹性和非弹性中子散射、XAS 数据以及详细的热电测量,总结了它们的性质研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
ACS Organic & Inorganic Au
ACS Organic & Inorganic Au 有机化学、无机化学-
CiteScore
4.10
自引率
0.00%
发文量
0
期刊介绍: ACS Organic & Inorganic Au is an open access journal that publishes original experimental and theoretical/computational studies on organic organometallic inorganic crystal growth and engineering and organic process chemistry. Short letters comprehensive articles reviews and perspectives are welcome on topics that include:Organic chemistry Organometallic chemistry Inorganic Chemistry and Organic Process Chemistry.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信