Isotope-Geochemical Characteristics of Fluids and Organic Matter of Rocks of Mud Volcanoes in the Northwestern (Azerbaijan) and Southeastern (Iran) Parts of the South Caspian Basin: A Comparative Analysis

IF 0.9 4区 地球科学 Q4 METEOROLOGY & ATMOSPHERIC SCIENCES
A. A. Feyzullayev, U. A. Movsumova
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Abstract

This article presents a comparative analysis of the isotope-geochemical characteristics of the products of activity of mud volcanoes (MVs) in the northwestern (Azerbaijan) and southeastern (Iran) parts of the South Caspian Basin (SCB). Gases of MVs in the studied regions are mainly of thermocatalytic origin, with the predominance of methane. High concentrations of nitrogen (up to 50%) are noted in the gases of some MVs in the Iranian sector. One distinctive feature of the MVs in the Azerbaijani part of the SCB is the presence of isotopically superheavy (>5‰) carbon dioxide, which is not typical for MVs in Iran. The waters of the MVs of Iran and most of the MVs of Azerbaijan are of the sodium chloride type. Isotopically heavy bicarbonate and carbonate ions, characteristic of the mud volcanic waters of Azerbaijan, are not typical for the volcanoes of the Iranian part of the SCB. Organic matter of rock ejecta of MVs in the Azerbaijani part of the SCB refers mainly to type II and type II–III kerogen, while in its Iranian part it is mainly type III kerogen. Mud volcanoes of Azerbaijan are characterized by a wide range of gas generation depths (10–16 km) and, accordingly, significant subvertical migration. The calculated maximum depth of the HC gas source in the Iranian part of the SCB does not exceed 12 km.

Abstract Image

南里海盆地西北部(阿塞拜疆)和东南部(伊朗)泥火山岩石流体和有机物质的同位素地球化学特征:比较分析
摘要 本文对南里海盆地西北部(阿塞拜疆)和东南部(伊朗)泥火山活动产物的同位素地球化学特征进行了比较分析。研究地区的泥火山气体主要来自热催化反应,以甲烷为主。在伊朗部分地区的一些煤层气中发现了高浓度氮气(高达 50%)。南中国海阿塞拜疆部分的低压气 体的一个显著特点是存在同位素超重(5‰)二氧化碳,这在伊朗的低压气 体中并不常见。伊朗中压水域和阿塞拜疆大部分中压水域的水质属于氯化钠型。阿塞拜疆泥质火山水特有的同位素重碳酸氢根离子和碳酸根离子,在南亚盆地伊朗部分的火山中并不常见。深海盆地阿塞拜疆部分的泥火山岩石喷出物中的有机物主要是第二类和第二至第三类角质,而伊朗部分的主要是第三类角质。阿塞拜疆泥火山的特点是气体生成深度范围广(10-16 千米),因此地下迁移量大。根据计算,阿塞拜疆泥火山伊朗部分的碳氢化合物气源最大深度不超过 12 公里。
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来源期刊
CiteScore
1.40
自引率
28.60%
发文量
56
审稿时长
6-12 weeks
期刊介绍: Izvestiya, Atmospheric and Oceanic Physics is a journal that publishes original scientific research and review articles on vital issues in the physics of the Earth’s atmosphere and hydrosphere and climate theory. The journal presents results of recent studies of physical processes in the atmosphere and ocean that control climate, weather, and their changes. These studies have possible practical applications. The journal also gives room to the discussion of results obtained in theoretical and experimental studies in various fields of oceanic and atmospheric physics, such as the dynamics of gas and water media, interaction of the atmosphere with the ocean and land surfaces, turbulence theory, heat balance and radiation processes, remote sensing and optics of both media, natural and man-induced climate changes, and the state of the atmosphere and ocean. The journal publishes papers on research techniques used in both media, current scientific information on domestic and foreign events in the physics of the atmosphere and ocean.
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