Classic Scottish sandstone concretions formed from hot water

Abstract

Large calcite-cemented sandstone concretions found in Middle Jurassic sandstones from the isles of Eigg and Skye are a striking feature of the Jurassic geology of the Inner Hebrides. Recent clumped isotope data unequivocally give concretionary calcite cementation temperatures above 50°C and up to 98°C. The high temperatures contrast with the mild thermal history of the enclosing less permeable Jurassic mudrocks. The clumped isotope data also enable calculation of the oxygen isotopic composition of the precipitating fluids: these included percolating rainwater that had interacted with Paleocene volcanics; then, later hot fluids of deeper, basinal origin, squeezed out of compacting mudrocks at depth as the Paleocene lava pile loaded the crust. There is thus direct connection between ‘Jurassic’ sedimentary features and the complex Paleocene volcanic history of the region.