Gamma-ray shielding analysis using the experimental measurements for copper(ii) sulfate-doped polyepoxide resins

IF 3.2 3区 化学 Q2 POLYMER SCIENCE
e-Polymers Pub Date : 2023-12-21 DOI:10.1515/epoly-2023-0142
K. A. Mahmoud, Mazen M. Binmujlli, M. W. Marashdeh, Mamduh J. Aljaafreh, Ahmad Saleh, M. Y. Hanfi
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Abstract

The present work aims to study the effect of the CuSO4 additive on the physical and radiation-shielding properties of polyepoxide resins. As a result, a series of four samples with the chemical composition xCuSO4 + (100 − x) (epoxy resin and hardener) was synthesized. The fabrication of samples was performed under atmospheric pressure and at room temperature. The density of the fabricated CuSO4-doped polyepoxides resin was measured experimentally using an MH-300A densimeter with an accuracy of 0.001 mg·cm−3. A narrow beam transmission method with an NaI (Tl) detector was used to evaluate and describe the effect of CuSO4 on the linear attenuation coefficient of the fabricated composites in the γ-ray energy interval, which ranged between 33 and 1,332 keV. The estimated results showed a high enhancement in the µ values that increased from 0.259 to 1.749 cm−1, raising the CuSO4 concentration from 0 to 40 wt% at a γ-photon energy of 33 keV. The enhancement in the µ values decreased with an increase in the γ-photon energy to 1,332 keV, whereas the µ values increased from 0.077 to 0.102 cm−1 with an increase in the CuSO4 concentration between 0 and 40 wt%, respectively. This showed that increased µ values positively affected the half-value thickness (Δ 0.5, cm), mean free path (λ, cm), lead equivalent thickness (Δ eq, cm), and the transmission factor (%); all of the mentioned parameters suffer a considerable decrease with increasing CuSO4 concentration between 0 and 40 wt%.
利用掺杂硫酸铜(ii)的聚环氧树脂的实验测量结果进行伽马射线屏蔽分析
本工作旨在研究 CuSO4 添加剂对聚环氧树脂的物理和辐射屏蔽性能的影响。因此,合成了一系列化学成分为 xCuSO4 + (100 - x) (环氧树脂和固化剂)的四种样品。样品的制作在常压和室温下进行。使用 MH-300A 密度计实验测量了掺杂了 CuSO4 的聚环氧树脂的密度,精度为 0.001 mg-cm-3。使用带有 NaI (Tl) 探测器的窄光束透射法评估和描述了 CuSO4 在 33 至 1,332 keV γ 射线能量区间内对所制复合材料线性衰减系数的影响。估计结果表明,在γ-光子能量为 33 keV 时,CuSO4 浓度从 0% 增加到 40 wt%,µ 值从 0.259 增加到 1.749 cm-1。随着 γ 光子能量增加到 1,332 keV,µ 值的增强幅度减小,而随着 CuSO4 浓度从 0% 增加到 40 wt%,µ 值分别从 0.077 cm-1 增加到 0.102 cm-1。这表明,µ 值的增加对半值厚度 (Δ 0.5, cm)、平均自由路径 (λ, cm)、铅当量厚度 (Δ eq, cm) 和透射系数 (%) 有积极影响;在 0 到 40 wt% 之间,随着 CuSO4 浓度的增加,上述所有参数都会大幅下降。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
e-Polymers
e-Polymers 化学-高分子科学
CiteScore
5.90
自引率
10.80%
发文量
64
审稿时长
6.4 months
期刊介绍: e-Polymers is a strictly peer-reviewed scientific journal. The aim of e-Polymers is to publish pure and applied polymer-science-related original research articles, reviews, and feature articles. It includes synthetic methodologies, characterization, and processing techniques for polymer materials. Reports on interdisciplinary polymer science and on applications of polymers in all areas are welcome. The present Editors-in-Chief would like to thank the authors, the reviewers, the editorial staff, the advisory board, and the supporting organization that made e-Polymers a successful and sustainable scientific journal of the polymer community. The Editors of e-Polymers feel very much engaged to provide best publishing services at the highest possible level.
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