Development of Activated Carbon Textiles Produced from Jute and Cotton Wastes for Electromagnetic Shielding Applications

IF 4 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Fibers Pub Date : 2023-12-13 DOI:10.3390/fib11120110
Sema Sert, Deniz Duran Kaya, Ayşegül Körlü
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引用次数: 0

Abstract

Increasing amounts of waste resulting from over-consumption carry substantial risks for human and environmental health, and disposing of this waste requires enormous amounts of energy. As a result, waste-to-wealth and circular economy approaches have gained attention in both academia and the commercial sector in recent years. Accordingly, this study aims to develop electromagnetic shielding materials by converting non-conductive waste textiles into conductive value-added product and porous fabrics by carbonizing the structure itself rather than by adding any conductive particles. To this end, the novel contribution of the present study is that waste textiles were converted into activated carbon in a shorter time and without compromising the integrity of the fibrous network via microwave pyrolysis without inert gas. Sulfuric acid was used as a dehydration and activation agent, suppressing the release of volatile organic substances and eliminating greenhouse gas emissions. This approach also increased product yield and reduced energy consumption and sample shrinkage. The structures of the activated carbon textile showed EMI shielding within 20–30 dB (99.9% attenuation) in the 1–6 GHz frequency range. The maximum SSE/t value of 950.71 dB·cm2·g−1 was obtained with the microwave post-treated activated carbon textile. Micropores were dominant characteristics of these materials, and pore diameters increased with increased acid concentration. The maximum surface area of 383.92 m2/g was obtained with 8% acid. Ultrasound treatment reduced water-energy consumption and cost. Only 5 min of microwave post-treatment increased textile conductivity and thermal stability and contributed positively to electromagnetic shielding.
利用黄麻和棉花废料生产的活性炭纺织品在电磁屏蔽领域的应用开发
过度消费所产生的越来越多的废物对人类和环境健康造成了巨大风险,而处理这些废物又需要大量能源。因此,变废为宝和循环经济的方法近年来在学术界和商界都受到了关注。因此,本研究旨在开发电磁屏蔽材料,通过碳化结构本身而非添加任何导电颗粒,将不导电的废弃纺织品转化为导电的高附加值产品和多孔织物。为此,本研究的新贡献是在不使用惰性气体的情况下,通过微波热解,在更短的时间内将废旧纺织品转化为活性炭,同时不损害纤维网的完整性。硫酸被用作脱水剂和活化剂,抑制了挥发性有机物质的释放,消除了温室气体排放。这种方法还提高了产品产量,降低了能耗和样品收缩率。活性碳纺织品的结构显示,在 1-6 GHz 频率范围内,电磁干扰屏蔽在 20-30 dB(衰减 99.9%)以内。经微波后处理的活性炭织物的最大 SSE/t 值为 950.71 dB-cm2-g-1。微孔是这些材料的主要特征,孔径随着酸浓度的增加而增大。8% 的酸可获得 383.92 m2/g 的最大表面积。超声波处理降低了水能消耗和成本。仅 5 分钟的微波后处理就能提高纺织品的导电性和热稳定性,并对电磁屏蔽起到积极作用。
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来源期刊
Fibers
Fibers Engineering-Civil and Structural Engineering
CiteScore
7.00
自引率
7.70%
发文量
92
审稿时长
11 weeks
期刊介绍: Fibers (ISSN 2079-6439) is a peer-reviewed scientific journal that publishes original articles, critical reviews, research notes and short communications on the materials science and all other empirical and theoretical studies of fibers, providing a forum for integrating fiber research across many disciplines. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. There is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Electronic files or software regarding the full details of the calculation and experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. The following topics are relevant and within the scope of this journal: -textile fibers -natural fibers and biological microfibrils -metallic fibers -optic fibers -carbon fibers -silicon carbide fibers -fiberglass -mineral fibers -cellulose fibers -polymer fibers -microfibers, nanofibers and nanotubes -new processing methods for fibers -chemistry of fiber materials -physical properties of fibers -exposure to and toxicology of fibers -biokinetics of fibers -the diversity of fiber origins
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